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Synthesis of [1,2]dithiolo[3,4-b]pyridines via the reaction of dithiomalondianilide with arylmethylidenemalononitriles

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Chemistry of Heterocyclic Compounds Aims and scope

6-Amino-4-aryl-7-phenyl-3-(phenylamino)-4,7-dihydro-3Н-[1,2]dithiolo[3,4-b]pyridine-5-carbonitriles were synthesized via the reaction of arylmethylidenemalononitriles with dithiomalonic acid dianilide in the presence of an excess of morpholine. The structure of 6-amino-4-(3,4-dimethoxyphenyl)-7-phenyl-3-(phenylamino)-4,7-dihydro-3Н-[1,2]dithiolo[3,4-b]pyridine-5-carbonitrile was studied by X-ray structural analysis.

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Notes

  1. Antiphase signals.

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Authors and Affiliations

  1. Kuban State University, 149 Stavropolskaya St., Krasnodar, 350040, Russia

    Victor V. Dotsenko, Sergey G. Krivokolysko & Konstantin A. Frolov

  2. Federal State Unitary Enteprise “IREA”, 3 Bogorodsky Shaft, Moscow, 107076, Russia

    Elena A. Chigorina

  3. Enamine Ltd., 67/45 Krasnotkatskaya St., Kiev, 02094, Ukraine

    Vitaliy V. Polovinko

  4. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St., Moscow, 119991, Russia

    Artem O. Dmitrienko & Ivan S. Bushmarinov

Authors
  1. Victor V. Dotsenko
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  2. Sergey G. Krivokolysko
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  3. Konstantin A. Frolov
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  4. Elena A. Chigorina
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  5. Vitaliy V. Polovinko
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  6. Artem O. Dmitrienko
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  7. Ivan S. Bushmarinov
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Corresponding author

Correspondence to Victor V. Dotsenko.

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2015, 51(4), 389–392

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Supporting information

The Supporting information file containing spectra and the full set of X-ray structural analysis data are available for authorized users. (PDF 5520 kb)

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Dotsenko, V.V., Krivokolysko, S.G., Frolov, K.A. et al. Synthesis of [1,2]dithiolo[3,4-b]pyridines via the reaction of dithiomalondianilide with arylmethylidenemalononitriles. Chem Heterocycl Comp 51, 389–392 (2015). https://doi.org/10.1007/s10593-015-1713-6

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  • DOI: https://doi.org/10.1007/s10593-015-1713-6

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