The reaction of imidazole and benzimidazole derivatives with 1-(iodomethyl)-1,1,3,3,3-pentamethyldisiloxane resulted in N 1,3-alkylation, cleavage of siloxane bonds by the evolved hydrogen iodide, and the formation of cyclic organosilicon iodides and triiodides.
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The work was performed with financial support from the Grants Council of President of the Russian Federation (NSh-3649.2014.3).
The main results were obtained by using the instrumentation at Baikal Analytical Collective Use Center of the Siberian Branch, Russian Academy of Sciences.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, 2015, 51(4), 381–384
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Zhilitskaya, L.V., Yarosh, N.O., Shagun, L.G. et al. Alkylation of imidazole and benzimidazole derivatives with 1-(iodomethyl)-1,1,3,3,3-pentamethyldisiloxane – a new method for the preparation of organocyclosiloxane iodides. Chem Heterocycl Comp 51, 381–384 (2015). https://doi.org/10.1007/s10593-015-1711-8
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DOI: https://doi.org/10.1007/s10593-015-1711-8