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Photo- and Thermochromic Spirans. 39. *Study of the Complexation of a New Crown-containing Benzoxazine Spiropyran with Metal Cations

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Chemistry of Heterocyclic Compounds Aims and scope

A new benzoxazinone spiropyran containing a crown ether fragment have been synthesized. This compound was studied by both experimental and theoretical methods. In contrast to previously studied analogs, photoinduced coloration is not observed. By irradiating this crown-containing spiropyran, only an E-Z isomerization reaction proceeds. Complexation of the closed spiropyran form runs in a solution containing a calcium salt. A hypsochromic shift of the long-wavelength maximum in the absorption spectrum is observed.

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Authors and Affiliations

  1. Scientific-Research Institute of Physical and Organic Chemistry, Southern Federal University, 194/2 Stachki Ave., Rostov-on-the-Don, 344090, Russia

    M. B. Lukyanova, B. S. Lukyanov & M. S. Korobov

  2. Chemical Faculty, Southern Federal University, 7 Zorge St., Rostov-on-the-Don, 344090, Russia

    S. O. Bezuglyi

  3. Southern Scientific Center, Russian Academy of Sciences, 41 Chekhova St., Rostov-on-the-Don, 344010, Russia

    I. V. Dorogan

Authors
  1. M. B. Lukyanova
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  2. B. S. Lukyanov
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  3. I. V. Dorogan
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  4. S. O. Bezuglyi
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  5. M. S. Korobov
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Correspondence to B. S. Lukyanov.

Additional information

For Communication 38, see [1].

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1951-1958, December, 2013.

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Lukyanova, M.B., Lukyanov, B.S., Dorogan, I.V. et al. Photo- and Thermochromic Spirans. 39. *Study of the Complexation of a New Crown-containing Benzoxazine Spiropyran with Metal Cations. Chem Heterocycl Comp 49, 1808–1814 (2014). https://doi.org/10.1007/s10593-014-1433-3

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  • DOI: https://doi.org/10.1007/s10593-014-1433-3

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