Skip to main content

Advertisement

Log in

Durable antibacterial and UV protective properties of cellulose fabric functionalized with Ag/TiO2 nanocomposite during dyeing with reactive dyes

  • Original Paper
  • Published:
Cellulose Aims and scope Submit manuscript

Abstract

The cellulose fabrics made from 100 % cotton with antibacterial and UV protective properties were successfully created by loading of Ag/TiO2 nanocomposite during and after dyeing with yellow, red and blue reactive dye. Blank dyeing (dyeing with all chemicals except dye) was performed to show that reactive dyes have an ability to increase the adsorption and adhesion of Ag/TiO2 nanocomposite on cotton fabrics. The colour of the samples before and after washing and exposure to artificial light was measured by reflectance spectroscopy. The presence of nanocomposite on samples was confirmed by scanning electron microscope. The increased adsorption capacity of cotton towards Ag/TiO2 nanocomposite due to the presence of reactive dyes was confirmed by measuring the quantity of silver using inductively coupled plasma mass spectroscopy. The same samples showed excellent UV protective properties with UV protection factor (UPF 50+), and excellent antibacterial properties against E. coli and S. aureus. Due to a good adhesion of nanocomposite on samples where loading of nanocomposite and dyeing with reactive dye was performed simultaneously, the samples retained their excellent protective properties after repetitive washing cycles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2

Similar content being viewed by others

References

  • Achachi A et al (2015) UV Radiation induces the epidermal recruitment of dendritic cells that compensate for the depletion of langerhans cells in human skin. J Invest Dermatol 135:2058–2067. doi:10.1038/jid.2015.118

    Article  CAS  Google Scholar 

  • Bradford CP (ed) (1986) The dyeing of cellulosic fibres. The Dyers’ Company Publications Trust. ISBN: 0-901956-43-0: 408

  • Czajkowski W, Paluszkiewicz J (2008) Synthesis of bifunctional monochlorotriazine reactive dyes increasing UV-protection properties of cotton fabrics. Fibres Text East Eur 16:122–126

    CAS  Google Scholar 

  • Damm C, Münstedt H, Rösch A (2008) The antimicrobial efficacy of polyamide 6/silver-nano- and microcomposites. Mater Chem Phys 108:61–66. doi:10.1016/j.matchemphys.2007.09.002

    Article  CAS  Google Scholar 

  • Dastjerdi R, Mojtahedi MRM, Shoshtari AM (2008) Investigating the effect of various blend ratios of prepared masterbatch containing Ag/TiO2 nanocomposite on the properties of bioactive continuous filament yarns. Fiber Polym 9:727–734. doi:10.1007/s12221-008-0114-1

    Article  CAS  Google Scholar 

  • Dastjerdi R, Montazer M, Shahsavan S (2010) A novel technique for producing durable multifunctional textiles using nanocomposite coating. Colloid Surf B 81:32–41. doi:10.1016/j.colsurfb.2010.06.023

    Article  CAS  Google Scholar 

  • De Gusseme B et al (2010) Biogenic silver for disinfection of water contaminated with viruses. Appl Environ Microbiol 76:1082–1087. doi:10.1128/aem.02433-09

    Article  Google Scholar 

  • Feng QL, Wu J, Chen GQ, Cui FZ, Kim TN, Kim JO (2000) A mechanistic study of the antibacterial effect of silver ions on Escherichia coli and Staphylococcus aureus. J Biomed Mater Res 52:662–668. doi:10.1002/1097-4636(20001215)52:4<662:aid-jbm10>3.0.co;2-3

    Article  CAS  Google Scholar 

  • Franci G, Falanga A, Galdiero S, Palomba L, Rai M, Morelli G, Galdiero M (2015) Silver nanoparticles as potential antibacterial agents. Molecules 20:8856–8874. doi:10.3390/molecules20058856

    Article  CAS  Google Scholar 

  • Gordon S, Hsieh YL (eds) (2007) Cotton: science and technology. Woodhead Publishing Limited, Cambridge

    Google Scholar 

  • Gorenšek M, Recelj P (2007) Nanosilver functionalized cotton fabric. Text Res J 77:138–141. doi:10.1177/0040517507076329

    Article  Google Scholar 

  • Gorenšek M, Recelj P (2009) Reactive dyes and nano-silver on PA6 micro knitted goods. Text Res J 79:138–146. doi:10.1177/0040517508091314

    Article  Google Scholar 

  • Gorenšek M, Gorjanc M, Bukošek V, Kovač J, Petrović Z, Puač N (2010) Functionalization of polyester fabric by Ar/N2 plasma and silver. Text Res J 80:1633–1642. doi:10.1177/0040517510365951

    Article  Google Scholar 

  • Gorjanc M, Bukošek V, Gorenšek M, Mozetič M (2010) CF4 plasma and silver functionalized cotton. Text Res J 80:2204–2213. doi:10.1177/0040517510376268

    Article  CAS  Google Scholar 

  • Gorjanc M, Kovač F, Gorenšek M (2012) The influence of vat dyeing on the adsorption of synthesized colloidal silver onto cotton fabrics. Text Res J 82:62–69. doi:10.1177/0040517511420754

    Article  CAS  Google Scholar 

  • Gorjanc M, Gorenšek M, Jovančić P, Mozetič M (2013) Multifunctional textiles—modification by plasma, dyeing and nanoparticles. In: Gunay M (ed) Eco-friendly textile dyeing and finishing. InTech, Rijeka, pp 3–31. doi:10.5772/3436

  • Gorjanc M, Jazbec K, Šala M, Zaplotnik R, Vesel A, Mozetič M (2014) Creating cellulose fibres with excellent UV protective properties using moist CF4 plasma and ZnO nanoparticles. Cellulose 21:3007–3021. doi:10.1007/s10570-014-0284-5

    Article  CAS  Google Scholar 

  • Grancarić AM, Tarbuk A, Botteri L (2014) Light conversion and scattering in UV protective textiles. Autex Res J 14:247–258. doi:10.2478/aut-2014-0025

    Google Scholar 

  • Ibrahim NA, Eid BM, Khalil HM (2015) Cellulosic/wool pigment prints with remarkable antibacterial functionalities. Carbohydr Polym 115:559–567. doi:10.1016/j.carbpol.2014.09.013

    Article  CAS  Google Scholar 

  • Ilić V, Šaponjić Z, Vodnik V, Potkonjak B, Jovančić P, Nedeljković J, Radetić M (2009) The influence of silver content on antimicrobial activity and color of cotton fabrics functionalized with Ag nanoparticles. Carbohydr Polym 78:564–569. doi:10.1016/j.carbpol.2009.05.015

    Article  Google Scholar 

  • Kim J, Kwon S, Ostler E (2009) Antimicrobial effect of silver-impregnated cellulose: potential for antimicrobial therapy. J Biol Eng 3:20. doi:10.1186/1754-1611-3-20

    Article  Google Scholar 

  • Klemenčič D, Simončič B, Tomšič B, Orel B (2010) Biodegradation of silver functionalised cellulose fibres. Carbohydr Polym 80:426–435. doi:10.1016/j.carbpol.2009.11.049

    Article  Google Scholar 

  • Lazić V, Vodnik V, Nedeljković J, Saponjić Z, Jovančić P, Radetić M (2013) Antibacterial and colorimetric evaluation of cotton fabrics dyed with direct dyes and loaded with Ag nanoparticles. Ind Textila 64:89–97

    Google Scholar 

  • Malešič J, Šala M, Šelih VS, Kočar D (2014) Evaluation of a method for treatment of iron gall ink corrosion on paper. Cellulose 21:2925–2936. doi:10.1007/s10570-014-0311-6

    Article  Google Scholar 

  • Montazer M, Seifollahzadeh S (2011) Enhanced self-cleaning, antibacterial and UV protection properties of nano TiO2 treated textile through enzymatic pretreatment. Photochem Photobiol 87:877–883. doi:10.1111/j.1751-1097.2011.00917.x

    Article  CAS  Google Scholar 

  • Nevell TP (1986) Cellulose—its structure and properties. In: Preston C (ed) The dyeing of cellulosic fibres. Dyer’s Company Publicatons Trust, West Yorkshire, pp 1–54

    Google Scholar 

  • Onar N, Aksit AC, Sen Y, Mutlu M (2011) Antimicrobial, UV-protective and self-cleaning properties of cotton fabrics coated by dip-coating and solvothermal coating methods. Fiber Polym 12:461–470. doi:10.1007/s12221-011-0461-1

    Article  CAS  Google Scholar 

  • Rimai DS, Quesnel DJ, Busnaina AA (2000) The adhesion of dry particles in the nanometer to micrometer-size range. Colloid Surf A 165:3–10. doi:10.1016/s0927-7757(99)00439-2

    Article  CAS  Google Scholar 

  • Rizk HF, Ibrahim SA, El-Borai MA (2015) Synthesis, fastness properties, color assessment and antimicrobial activity of some azo reactive dyes having pyrazole moiety. Dyes Pigment 112:86–92. doi:10.1016/j.dyepig.2014.06.026

    Article  CAS  Google Scholar 

  • Rudolf Chemie (2007) The ultimate hygienic finish for textiles. Rudolf info 5/07: 12

  • Selvam S, Sundrarajan M (2012) Functionalization of cotton fabric with PVP/ZnO nanoparticles for improved reactive dyeability and antibacterial activity. Carbohydr Polym 87:1419–1424. doi:10.1016/j.carbpol.2011.09.025

    Article  CAS  Google Scholar 

  • Shateri-Khalilabad M, Yazdanshenas ME (2013) Bifunctionalization of cotton textiles by ZnO nanostructures: antimicrobial activity and ultraviolet protection. Text Res J 83:993–1004. doi:10.1177/0040517512468812

    Article  Google Scholar 

  • Sun RWY, Chen R, Chung NPY, Ho CM, Lin CLS, Che CM (2005) Silver nanoparticles fabricated in Hepes buffer exhibit cytoprotective activities toward HIV-1 infected cells. Chem Commun. doi:10.1039/b510984a

    Google Scholar 

  • Sundaresan K, Sivakumar A, Vigneswaran C, Ramachandran T (2012) Influence of nano titanium dioxide finish, prepared by sol-gel technique, on the ultraviolet protection, antimicrobial, and self-cleaning characteristics of cotton fabrics. J Ind Text 41:259–277. doi:10.1177/1528083711414962

    Article  CAS  Google Scholar 

  • Tarbuk A, Grancarić AM, Šitum M, Martinis M (2010) UV clothing and skin cancer. Coll Antropol 34:179–183

    Google Scholar 

  • Tomšič B, Simončič B, Orel B, Žerjav M, Schroers H, Simončič A, Samardžija Z (2009) Antimicrobial activity of AgCl embedded in a silica matrix on cotton fabric. Carbohydr Polym 75:618–626. doi:10.1016/j.carbpol.2008.09.013

    Article  Google Scholar 

  • Ugur SS, Sariisik M, Aktas H (2011) Nano-TiO2 based multilayer film deposition on cotton fabrics for UV-protection. Fiber Polym 12:190–196. doi:10.1007/s12221-011-0190-5

    Article  CAS  Google Scholar 

  • Ursache M, Loghin C, Muresan R, Cerempei A, Muresan A (2011) Investigation on the effects of antibacterial finishes on dyed cotton knitted fabrics. Tekst Konfeksiyon 21:249–256

    Google Scholar 

  • Yuranova T, Rincon AG, Pulgarin C, Laub D, Xantopoulos N, Mathieu HJ, Kiwi J (2006) Performance and characterization of Ag-cotton and Ag/TiO2 loaded textiles during the abatement of E. coli. J Photochem Photobiol A 181:363–369. doi:10.1016/j.jphotochem.2005.12.020

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The research was financially supported by Slovenian Research Agency (programmes P2-0213 and P1-0034).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Marija Gorjanc.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gorjanc, M., Šala, M. Durable antibacterial and UV protective properties of cellulose fabric functionalized with Ag/TiO2 nanocomposite during dyeing with reactive dyes. Cellulose 23, 2199–2209 (2016). https://doi.org/10.1007/s10570-016-0945-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10570-016-0945-7

Keywords

Navigation