Abstract
The elasticity of the polyacrylamide (PAAm)-kappa carrageenan (κC) composite was determined as a function of (w/v-%) κC content at 40 °C. The gel composites studied contained various percentages (w/v-%) of κC. The elasticity of the swollen PAAm-κC composite was characterized by using the tensile testing technique. This study investigated the elasticity and the percolation threshold of PAAm-κC composite as a function of κC content. It is understood that the compressive elastic modulus decreases up to 1 (w/v-%) of κC and then increases at contents above 1(w/v-%) of κC. The critical exponent of elasticity y was determined between 1 and 1.6 (w/v-%) of κC and found to be 0.68. The observed elastic percolation threshold is consistent with the suggested values of the superelastic percolation network.
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References
Aktaş DK, Evingür GA, Pekcan Ö (2006) Universal behaviour of gel formation from acrylamide-carrageenan mixture around the gel point: a fluorescence study. J Biomol Struct Dyn 24(1):83–90
Anseth KS, Bowman CN, Peppas LB (1996) Mechanical properties of hydrogels and their experimental determination. Biomaterials 17:1647–1657
Arbabi S, Sahimi M (1993) Mechanics of disordered solids. I. percolation on elastic networks with central forces. Phys Rev B 47(2):695–702
Berkowitz B, Balberg I (1993) Percolation theory and its application to groundwater hydrology. Water Res 29(4):775–794
Çakır E, Foegeding EA (2011) Combining protein micro protein micro phase separation and protein-polysaccharide segregative phase separation to produce gel structures. Food Hydrocoll 25:1538–1546
Colby RH, Gillmor JR, Rubinstein M (1993) Dynamics of near critical polymer gels. Phys Rev E 48(5):3712–3716
de Gennes PG (1976) On the relation between percolation theory and the elasticity of gels. Le J de Phys Lett 37:L1–L2
Erman B, Flory PJ (1986) Critical phenomena and transitions in swollen polymer networks and in linear macromolecules. Macromol 19:2342–2353
Evingür GA, Pekcan Ö (2011) Drying of polyacrylamide composite gels formed with various kappa carrageenan content. J Fluo 21:1531–1537
Evingür GA, Pekcan Ö (2012a) Elastic percolation of swollen polyacrylamide (PAAm)-multiwall carbon nanotubes (MWNTs) composite. Ph Transitions 85:553–564
Evingür GA, Pekcan Ö (2012b) Temperature effect on the swelling of PAAm–kcarrageenan composites. J Appl Polym Sci 123:1746–1754
Feng S, Sen PN (1984) Percolation on elastic networks: new exponent and threshold. Phys Rev Lett 52(3):216–219
Friedrich K, Fakirov S, Zhang Z (2005) Polymer composites from nano to macro scale. Springer, USA
Kantor Y, Webman I (1984) Elastic properties of random percolating systems. Phys Rev Lett 52(21):1891–1894
Loret C, Ribelles P, Lundin L (2009) Mechanical properties of k-carrageenan in high concentration of sugar solutions. Food Hydrocoll 23:823–832
Muniz EC, Geuskens G (2001) Compressive elastic modulus of polyacrylamide hydrogels and semi-IPN’s with poly (N-isoproplacrylamide). Macromolecules 34:4480–4484
Nielsen LE, Lawrence RF (1994) Mechanical properties of polymers and composites. Marcel Dekker, New York
Rubinstein RH, Colby H (1994) Elastic modulus and equilibrium swelling of near critical gels. Macromolecules 27:3184–3190
Sahimi M (1994) Application of percolation theory. Taylor and Francis, London
Schriemer HP, Pachet NG, Page JH (1996) Ultrasonic investigation of the vibrational modes of a sintered glass-bead percolation system. Waves Random Media 6:361–386
Spagnol C, Rodrigues FHA, Pereira AGB, Fajardo AR, Rubira AF, Muniz EC (2012a) Superabsorbent hydrogel composite made of cellulose nanofibrils and chitosan-graft-poly (acrylic acid). Carbohydr Polym 87(3):2038–2045
Spagnol C, Rodrigues FHA, Pereira AGB, Fajardo AR, Rubira AF, Muniz EC (2012b) Superabsorbent hydrogel nanocomposites based on starch-g-poly(sodium acrylate) matrix filled with cellulose nanowhiskers. Cellulose 19(4):1225–1237
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We thank Dr. Argun Talat Gökçeören for the mechanical measurements.
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Evingür, G.A., Pekcan, Ö. Superelastic percolation network of polyacrylamide (PAAm)–kappa carrageenan (κC) composite. Cellulose 20, 1145–1151 (2013). https://doi.org/10.1007/s10570-013-9903-9
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DOI: https://doi.org/10.1007/s10570-013-9903-9