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Manganes-Porphyrin as Efficient Enantioselective Catalyst for Aerobic Epoxidation of Olefins

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Abstract

A chiral manganese porphyrin, [Mn(TCPP-Ind)Cl], was synthesized using cis-1-amino-2-indanol substituent. It showed remarkable catalytic activity and enantioselectivity in the epoxidation of olefins with O2/RCHO. Terminal olefins and styrene derivatives were successfully oxidized (> 99% ee). TON of 73,000 was achieved in the epoxidation of α-methylstyrene after five times recycling.

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Acknowledgements

We thank Professor M. Vahedpour for helpful advice and discussions. The authors are grateful for financial support from the University of Zanjan.

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Authors and Affiliations

  1. Department of Chemistry, University of Zanjan, 45195-313, Zanjan, Islamic Republic of Iran

    Afsaneh Farokhi, Kayhaneh Berijani & Hassan Hosseini-Monfared

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  1. Afsaneh Farokhi
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  2. Kayhaneh Berijani
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  3. Hassan Hosseini-Monfared
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Correspondence to Hassan Hosseini-Monfared.

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Farokhi, A., Berijani, K. & Hosseini-Monfared, H. Manganes-Porphyrin as Efficient Enantioselective Catalyst for Aerobic Epoxidation of Olefins. Catal Lett 148, 2608–2618 (2018). https://doi.org/10.1007/s10562-018-2447-8

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