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Highly Efficient and Convenient Supported Ionic Liquid TiCl5-DMIL@SiO2@Fe3O4-Catalyzed Cycloaddition of CO2 and Epoxides to Cyclic Carbonates

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Abstract

A series of silica coated magnetic nanoparticles supported ILs were prepared, characterized and their catalytic performances in cycloaddition of CO2 to epoxides were investigated. The influences of various reaction parameters including catalyst selection, catalyst amount, reaction time, and reaction temperature were studied. Research shows that TiCl5-DMIL@SiO2@Fe3O4 could be used as the highest efficient catalyst in cycloaddition of CO2 and epoxides to gives the corresponding cyclic carbonates. Good to excellent yields were achieved for this reaction under mild conditions. The heterogeneous supported catalyst is easily recoverable by filtration, and could be used for five consecutive runs without significant loss in catalytic activity.

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Acknowledgements

The authors are grateful to the National Natural Science Foundation of China (No. 21506115) for financial support.

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Authors and Affiliations

  1. College of Materials and Chemical Engineering, China Three Gorges University, Yichang, 443002, People’s Republic of China

    Yu Lin Hu

  2. Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, China Three Gorges University, Yichang, 443002, People’s Republic of China

    Yu Lin Hu

  3. College of Chemistry and Environmental Engineering, Yancheng Teachers University, Yancheng, 224002, People’s Republic of China

    Rong Xing

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  1. Yu Lin Hu
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  2. Rong Xing
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Correspondence to Yu Lin Hu.

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Hu, Y.L., Xing, R. Highly Efficient and Convenient Supported Ionic Liquid TiCl5-DMIL@SiO2@Fe3O4-Catalyzed Cycloaddition of CO2 and Epoxides to Cyclic Carbonates. Catal Lett 147, 1453–1463 (2017). https://doi.org/10.1007/s10562-017-2051-3

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  • DOI: https://doi.org/10.1007/s10562-017-2051-3

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