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Acetic Acid Synthesis from Ethanol: Describing the Synergy Between PdO and m-ZrO2

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Abstract

The PdO and m-ZrO2 oxides show different catalytic properties which are not only complementary but also relevant for the ethanol selective oxidation. Due to the spillover of the oxygenated intermediates from PdO to m-ZrO2 and vice versa these compounds are able to generate a promising system for ethanol oxidation to acetic acid.

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Acknowledgements

The authors acknowledge to the LACAT/INT staff for the characterization analyses, CETEM staff for the ICP-OES results and Saint-Gobain NorPro for supplied of m-ZrO2 sample as well. PPPR is grateful to CAPES for a scholarship.

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Authors and Affiliations

  1. Divisão de Catálise e Processos Químicos, Instituto Nacional de Tecnologia, Av Venezuela 82, 518, Rio de Janeiro, RJ, 20081-312, Brazil

    Philipe P. P. Reis, Priscila C. Zonetti & Lucia G. Appel

  2. Departamento de Engenharia Química e de Petróleo, Universidade Federal Fluminense, Rua Passos da Pátria, n° 156, Campus Praia Vermelha, Bloco E - Sala 231, Niterói, RJ, 24210-240, Brazil

    Philipe P. P. Reis & Fabio B. Passos

Authors
  1. Philipe P. P. Reis
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  2. Priscila C. Zonetti
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  3. Fabio B. Passos
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  4. Lucia G. Appel
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Correspondence to Lucia G. Appel.

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Reis, P.P.P., Zonetti, P.C., Passos, F.B. et al. Acetic Acid Synthesis from Ethanol: Describing the Synergy Between PdO and m-ZrO2 . Catal Lett 147, 821–827 (2017). https://doi.org/10.1007/s10562-017-2001-0

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  • DOI: https://doi.org/10.1007/s10562-017-2001-0

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