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Synthesis and Characterization of Pd Schiff Base Complex Immobilized onto Functionalized Nanoporous MCM-41 and its Catalytic Efficacy in the Suzuki, Heck and Stille Coupling Reactions

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Abstract

The present work describes the use of palladium-vanillin-Schiff-base complex immobilized on MCM-41 nanostructure as efficient catalyst for the Suzuki–Miyaura, Stille and Mizoroki–Heck reactions of several aryl halides under aerobic conditions. All the reactions were carried out in green solvents (H2O and PEG-400). The developed procedure results bring several benefits such as uses of inexpensive and non-toxic ligand (vanillin), easy catalyst/product separation and catalyst recycling. The catalyst can be reused at least for five consecutive cycles without a significant loss of its catalytic activity or metal leaching.

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Acknowledgements

Authors thank the research facilities of Ilam University, Ilam, Iran, for financial support of this research project.

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Correspondence to Mohsen Nikoorazm.

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Khanmoradi, M., Nikoorazm, M. & Ghorbani-Choghamarani, A. Synthesis and Characterization of Pd Schiff Base Complex Immobilized onto Functionalized Nanoporous MCM-41 and its Catalytic Efficacy in the Suzuki, Heck and Stille Coupling Reactions. Catal Lett 147, 1114–1126 (2017). https://doi.org/10.1007/s10562-016-1957-5

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  • DOI: https://doi.org/10.1007/s10562-016-1957-5

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