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Correlation of Kinetic and Rheological Data for Flexible Nanoparticle Catalysis in the Reaction of Piperidine with PS−

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Abstract

The effect of apparent catalysis at different concentration of flexible nanoparticles (FN), (FN = CTABr|MX|H2O) of piperidine with phenyl salicylate ion when substituted sodium phenolate [MX] ≠ 0 at 35 °C is discussed in this paper. The observed data (kobs vs. [MX]) have been discussed quantitatively based on pseudophase micellar (PM) model. Such data treatment gives relative micellar binding constants of counterion X− and Br−(R BrX ) with FN. The effects of [MX] on the kobs have been coherence in terms of empirical equation and rheological data. The large catalytic effect of FN on the rate of piperidinolysis of PS− and rheological evidence of micellar structure correlate to the relative counterion binding constant, R BrX .

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Acknowledgments

The authors would like to offer our deep gratitude to Malaya University and Malaysian Higher Education Ministry for financial support (UM.C/HIR/MOHE/SC/07) and Bright Sparks Scholarship (BSP/APP/0889/2012).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Malaya, 50603, Kuala Lumpur, Malaysia

    Khalisanni Khalid, Muhammad Azri Mohd Noh, Sharifuddin Md. Zain & M. Niyaz Khan

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  1. Khalisanni Khalid
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  2. Muhammad Azri Mohd Noh
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  3. Sharifuddin Md. Zain
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  4. M. Niyaz Khan
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Correspondence to Khalisanni Khalid or M. Niyaz Khan.

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Khalid, K., Noh, M.A.M., Zain, S.M. et al. Correlation of Kinetic and Rheological Data for Flexible Nanoparticle Catalysis in the Reaction of Piperidine with PS− . Catal Lett 146, 960–967 (2016). https://doi.org/10.1007/s10562-016-1715-8

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