Abstract
An effective and rapid procedure to synthesize hierarchical MOR (Hi-MOR) nanosheets by self-assembly between subnanocrystals and organic templates was reported. The hierarchical pore systems provided a large quantity of Brønsted acid sites. Compared with conventional mordenite, Hi-MOR showed higher activity, xylene selectivity and longer catalytic life in the reaction of toluene disproportionation, thanks to its excellent diffusion from hierarchical structure.
Graphical Abstract
Hierarchical morednite (Hi-MOR) nanosheets were synthesized by self-assembly between subnanocrystals and organic templates.
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References
Corma A (1997) Chem Rev 97:2373
Davis ME (2002) Nature 417:813
Cundy CS, Cox PA (2003) Chem Rev 103:663
Choi M, Na K, Kim J, Sakamoto Y, Terasaki O, Ryoo R (2009) Nature 461:246
Leng K, Wang Y, Hou C, Lancelot C, Lamonier C, Rives A, Sun Y (2013) J Catal 306:100
Tosheva L, Valtchev VP (2005) Chem Mater 17:2494
Na K, Choi M, Park W, Sakamoto Y, Terasaki O, Ryoo R (2010) J Am Chem Soc 13:4169
Kresge C, Leonowicz M, Roth W, Vartuli J, Beck J (1992) Nature 359:710
Xiao FS, Wang L, Yin C, Lin K, Di Y, Li J, Xu R, Su DS, Schlögl R, Yokoi T (2006) Angew Chem 118:3162
Na K, Jo C, Kim J, Cho K, Jung J, Seo Y, Messinger RJ, Chmelka BF, Ryoo R (2011) Science 333:328
Milina M, Mitchell S, Crivelli P, Cooke D, Pérez-Ramírez J (2014) Nat Commun 5:3922
Groen JC, Bach T, Ziese U, Paulaime-van Donk AM, de Jong KP, Moulijn JA, Pérez-Ramírez J (2005) J Am Chem Soc 127:1079
Verboekend D, Vilé G, Pérez-Ramírez J (2012) Adv Funct Mater 22:916
Meng X, Nawaz F, Xiao FS (2009) Nano Today 4:292
Chen H, Wydra J, Zhang X, Lee P-S, Wang Z, Fan W, Tsapatsis M (2011) J Am Chem Soc 133:12390
Wang H, Pinnavaia TJ (2006) Angew Chem Int Edit 45:7603
Chung KH (2008) Micropor Mesopor Mater 111:544
Li X, Prins R, van Bokhoven JA (2009) J Catal 262:257
van Laak AN, Sagala SL, Zečević J, Friedrich H, de Jongh PE, de Jong KP (2010) J Catal 276:170
Jo C, Jung J, Shin HS, Kim J, Ryoo R (2013) Angew Chem 125:10198
Kim J, Jo C, Lee S, Ryoo R (2014) J Mater Chem A 2:11905
Liu Y, Zhao N, Xian H, Cheng Q, Tan Y, Tsubaki N, Li X (2015) ACS Appl Mater Inter 7:8398
Inayat A, Knoke I, Spiecker E, Schwieger W (2012) Angew Chem Int Edit 51:1962
Leofanti G, Padovan M, Tozzola G, Venturelli B (1998) Catal Today 41:207
Liu M, Li J, Jia W, Qin M, Wang Y, Tong K, Chen H, Zhu Z (2015) RSC Adv 5:9237
Chen G, Jiang L, Wang L, Zhang J (2010) Micropor Mesopor Mater 134:189
Odedairo T, Balasamy R, Al-Khattaf S (2011) Ind Eng Chem Res 50:3169
Scherzer J (1978) J Catal 54:285
Tromp M, Van Bokhoven J, Oostenbrink M, Bitter J, De Jong K, Koningsberger D (2000) J Catal 190:209
Acknowledgments
The authors would like to thank National Natural Science Foundation of China (Nos. 20873091 and U1362103) for the financial support. And the authors would like to thank Dr. Dongmei Jia and Dr. van Bokhoven for their constructive comments which helped us to improve the manuscript.
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Liu, M., Jia, W., Li, J. et al. Catalytic Properties of Hierarchical Mordenite Nanosheets Synthesized by Self-Assembly Between Subnanocrystals and Organic Templates. Catal Lett 146, 249–254 (2016). https://doi.org/10.1007/s10562-015-1632-2
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DOI: https://doi.org/10.1007/s10562-015-1632-2