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One-Pot Synthesis of Monodisperse Palladium Tin Nanoparticles with Controlled Composition and Size and Its Catalytic Ability Study

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Abstract

We have developed a novel one-pot synthetic procedure for monodisperse palladium tin bimetallic alloy nanoparticles (NPs) with tunable compositions and sizes by the co-reduction of tin(II) acetate and palladium(II) bromide in the presence of oleylamine and trioctylphosphine. These NPs loaded on active carbon (PdSn/C) were used as active catalysts for Heck reactions, and exhibited composition dependent catalytic activities. Among these nanocatalysts, Pd63Sn37 NPs showed the best catalytic performance which is even superior to pure Pd NPs.

Graphical Abstract

PdSn NPs with controlled compositions and sizes were synthesized and characterized systematically, and Pd63Sn37/C NPs showed the best catalytic ability and stability that is even superior to pure Pd NPs with higher catalytic activity and stability in multi-recycled Heck reactions.

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Acknowledgments

This work is supported by Fundamental Research Funds for the Central Universities (CUG120802).

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Authors and Affiliations

  1. Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan, 430074, People’s Republic of China

    Yong Li, Yu Dai & Xi-ke Tian

Authors
  1. Yong Li
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  2. Yu Dai
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  3. Xi-ke Tian
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Corresponding author

Correspondence to Xi-ke Tian.

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Li, Y., Dai, Y. & Tian, Xk. One-Pot Synthesis of Monodisperse Palladium Tin Nanoparticles with Controlled Composition and Size and Its Catalytic Ability Study. Catal Lett 145, 1837–1844 (2015). https://doi.org/10.1007/s10562-015-1593-5

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  • DOI: https://doi.org/10.1007/s10562-015-1593-5

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