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β-Cyclodextrin: A Biomimetic Catalyst used for the Synthesis of 4H-chromene-3-carbonitrile and Tetrahydro-1H-xanthen-1-one Derivatives

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Abstract

An efficient and facile protocol has been documented for the synthesis of 4H-chromene and xanthen-1-one derivatives via a three component one pot reaction of salicyladehyde, malononitrile/dimedone and indole utilizing biomimetic catalyst. Affiliation between biomimetic and organocatalyst exhibits a versatile and high catalytic activity emerging to be a sustainable alternative to other catalysts. The significant features of this protocol are compatibility with various types of indole and active-methylene compound, accomplishment of high yields, cleaner reaction condition and avoidance of the use of costly catalysts. Recyclability of β-cyclodextrin a “biomimetic catalyst” is a significant feature of this protocol.

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Acknowledgments

The author Pratibha Rai and Madhulika Srivastava grateful to UGC, New Delhi, for the award of Senior Research Fellowship and Snehlata Yadav thankful to UGC, New Delhi, for the award of Research Fellowship. We also sincerely thank SAIF, Punjab University, Chandigarh, for providing micro-analyses and spectra.

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Correspondence to Jagdamba Singh.

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Rai, P., Srivastava, M., Yadav, S. et al. β-Cyclodextrin: A Biomimetic Catalyst used for the Synthesis of 4H-chromene-3-carbonitrile and Tetrahydro-1H-xanthen-1-one Derivatives. Catal Lett 145, 2020–2028 (2015). https://doi.org/10.1007/s10562-015-1588-2

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