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An Efficient Synthesis of Coumarin Derivatives Using a SBA-15 Supported Cobalt(II) Nanocatalyst

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Abstract

The catalytic performance of highly active cobalt(II) supported on mesoporous SBA-15 materials for the Pechmann reaction was investigated. SBA-15 supported cobalt(II) nanocatalyst was found to be efficient and easily recoverable in the Pechmann reaction of phenols and β-ketoesters to their corresponding coumarin derivatives under solvent-free conditions. The supported cobalt catalyst could be easily recovered after reaction completion and reused twelve times with an excellent durability and without any noticeable loss in activity.

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Acknowledgments

Fatemeh Rajabi is grateful to Payame Noor University for support of this work. Afsaneh Feiz gratefully acknowledges financial support from Research Council of Shahid Beheshti University for a research visit to Universidad de Cordoba (Spain).

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Correspondence to Fatemeh Rajabi.

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Rajabi, F., Feiz, A. & Luque, R. An Efficient Synthesis of Coumarin Derivatives Using a SBA-15 Supported Cobalt(II) Nanocatalyst. Catal Lett 145, 1621–1625 (2015). https://doi.org/10.1007/s10562-015-1544-1

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  • DOI: https://doi.org/10.1007/s10562-015-1544-1

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