Abstract
The catalytic performance of highly active cobalt(II) supported on mesoporous SBA-15 materials for the Pechmann reaction was investigated. SBA-15 supported cobalt(II) nanocatalyst was found to be efficient and easily recoverable in the Pechmann reaction of phenols and β-ketoesters to their corresponding coumarin derivatives under solvent-free conditions. The supported cobalt catalyst could be easily recovered after reaction completion and reused twelve times with an excellent durability and without any noticeable loss in activity.
Graphical Abstract
Similar content being viewed by others
References
Clark J, Sheldon R, Raston C, Poliakoff M, Leitner W (2014) Green Chem 16:18
Ahadi S, Zolghadr M, Khavasi HR, Bazgir A (2013) Org Biomol Chem 11:279
Nofal ZM, El-Masry H, Fahmy HH, Sarhan I (1997) Egypt J Pharm Sci 38:1
Nofal ZM, El-Zahar MI, Abd-El-Karim SS (2000) Molecules 5:99
Romanelli GP, Bennardi D, Ruiz DM, Baronetti G, Thomas HJ, Autino JC (2004) Tetrahedron Lett 45:8935
Yavari I, Hekmat-Shoar R, Zonouzi A (1998) Tetrahedron Lett 39:2391
Donnelly BJ, Donnelly DMX, O’Sullivan AM (1968) Tetrahedron 24:2617
Bigi F, Chesini L, Maggi R, Sartori G (1999) J Org Chem 64:1033
Sethna SM, Phadke R (1953) Org React 7:1
Canter FW, Curd FH, Robertson A (1931) J Chem Soc 1245
Woods LL, Sapp J (1962) J Org Chem 27:3703
Niharika P, Ramulu BV, Satyanarayana G (2014) Org Biomol Chem 12:4347
Valizadeh H, Shockravi A (2005) Tetrahedron Lett 46:3501
Subhas Bose D, Rudradas AP, Hari Babu M (2002) Tetrahedron Lett 43:9195
Smitha G, Sanjeeva Reddy CH (2004) Synthetic Commun 34:3997
Alexander VM, Bhat RP, Samant SD (2005) Tetrahedron Lett 46:6957
Soleimani E, Khodaei MM, Batooie N, Samadi S (2012) J Heterocyclic Chem 49:409
Singhal S, Jain SL, Sain B (2008) Heterocycles 75:1205
Rafiee E, Fakhri A, Joshaghani M (2013) J Heterocyclic Chem 50:1121
Dabiri M, Salehi P, Zolfigol MA, Baghbanzadeh M (2007) Heterocycles 71:677
Rajabi F, Luque R, Clark JH, Karimi B, Macquarrie DJ (2011) Catal Commun 12:510
Rajabi F, Luque R, Serrano-Ruiz JC (2012) Chem Biodivers 9:1823
Rajabi F, Nourian S, Ghiassian S, Balu AM, Saidi MR, Serrano-Ruiz JC, Luque R (2011) Green Chem 13:3282
Acknowledgments
Fatemeh Rajabi is grateful to Payame Noor University for support of this work. Afsaneh Feiz gratefully acknowledges financial support from Research Council of Shahid Beheshti University for a research visit to Universidad de Cordoba (Spain).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Rajabi, F., Feiz, A. & Luque, R. An Efficient Synthesis of Coumarin Derivatives Using a SBA-15 Supported Cobalt(II) Nanocatalyst. Catal Lett 145, 1621–1625 (2015). https://doi.org/10.1007/s10562-015-1544-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-015-1544-1