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An efficient heterogeneous catalytic method for the N-arylation of pyrrole and other N-heterocycles

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Abstract

4 Å molecular sieve modified with copper(0) or copper(II) is an efficient heterogeneous catalyst for the arylation of pyrrole and some other heterocycles with iodo- or bromoarenes, Cs2CO3 base and pyrrole (or DMF) solvent. The catalysts can be easily prepared and are reusable.

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Authors and Affiliations

  1. MTA-BME Organic Chemical Technology Research Group, Hungarian Academy of Sciences, Budapest, 1111, Hungary

    János Németh

  2. Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Műegyetemrkp. 3, Budapest, 1111, Hungary

    Nóra Debreczeni & Zoltán Hell

  3. Department of Chemical and Environmental Process Engineering, Budapest University of Technology and Economics, Budapest, 1521, Hungary

    Iván Gresits

  4. Bálint Analitika Kft, Fehérvári út, 144, Budapest, 1116, Hungary

    Mária Bálint

Authors
  1. János Németh
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  2. Nóra Debreczeni
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  3. Iván Gresits
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  4. Mária Bálint
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  5. Zoltán Hell
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Corresponding author

Correspondence to Zoltán Hell.

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Németh, J., Debreczeni, N., Gresits, I. et al. An efficient heterogeneous catalytic method for the N-arylation of pyrrole and other N-heterocycles. Catal Lett 145, 1113–1119 (2015). https://doi.org/10.1007/s10562-015-1523-6

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  • DOI: https://doi.org/10.1007/s10562-015-1523-6

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