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The Influence of Pd Particles Distribution Position on Pd/CNTs Catalyst for Acetylene Selective Hydrogenation

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Abstract

The structure and catalytic properties of Pd catalyst supported on the outer surface or inner surface of carbon nanotubes (CNTs) have been investigated by using various experimental techniques combined with acetylene selective hydrogenation tests. It has been shown that Pd/CNTs-out catalyst exhibits higher ethylene selectivity than Pd/CNTs-in catalyst for acetylene selective hydrogenation. The electron interaction between CNTs support and palladium particles is responsible for higher ethylene selectivity over Pd/CNTs-out catalyst.

Graphical Abstract

It is found that Pd/CNTs-out catalyst exhibits higher ethylene selectivity than Pd/CNTs-in catalyst for acetylene selective hydrogenation. The electron interaction between CNTs support and palladium particles is responsible for higher ethylene selectivity over Pd/CNTs-out catalyst.

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Acknowledgments

This work was jointly supported by Natural Science Foundation of Jiangsu Province (BK2010304) and NSFC (20833002).

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Authors and Affiliations

  1. Key Laboratory of Mesoscopic Chemistry of MOE, Jiangsu Provincial Key Laboratory of Nanotechnology, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, China

    Haimeng Lu, Bolian Xu, Xizhang Wang, Zheng Hu & Yining Fan

  2. Yangzhou Institute of Chemistry and Chemical Engineering, Nanjing University, Yangzhou, 211900, China

    Haimeng Lu, Bolian Xu & Yining Fan

Authors
  1. Haimeng Lu
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  2. Bolian Xu
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  3. Xizhang Wang
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  4. Zheng Hu
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  5. Yining Fan
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Corresponding authors

Correspondence to Bolian Xu or Yining Fan.

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Lu, H., Xu, B., Wang, X. et al. The Influence of Pd Particles Distribution Position on Pd/CNTs Catalyst for Acetylene Selective Hydrogenation. Catal Lett 144, 2198–2203 (2014). https://doi.org/10.1007/s10562-014-1388-0

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  • DOI: https://doi.org/10.1007/s10562-014-1388-0

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