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Visible Light-Accelerated Depolymerisation of Starch Under Fenton Conditions and Preparation of Calcium Sequestering Compounds

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Abstract

Oxidation of starch under Fenton conditions leads to a mixture of acids having Ca sequestering properties. The efficiency of the process increases under visible light irradiation; this is mainly due to the improvement of the depolymerization of the substrate. Whatever the experimental conditions, that is Fenton or photo-Fenton, the oxidation products promote the oxidation step.

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Notes

  1. The 1,000 W lamp was used in order to raise the temperature progressively from RT to 60 °C over 130–150 min and to follow the gelatinization process.

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Acknowledgments

The authors are indebted to ADEME (BIP program) and CNRS for financial support.

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Authors and Affiliations

  1. Green Chemistry Department, Agro-Industrie Recherches et Développements, Route de Bazancourt, 51110, Pomacle, France

    Caroline Laugel, Boris Estrine & Sinisa Marinkovic

  2. Institut de Chimie Moléculaire de Reims, UMR 7312, CNRS-Université de Reims Champagne-Ardenne, UFR des Sciences Exactes et Naturelles, 51100, Reims, France

    Caroline Laugel, Jean Le Bras, Norbert Hoffmann & Jacques Muzart

Authors
  1. Caroline Laugel
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  2. Boris Estrine
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  3. Jean Le Bras
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  4. Norbert Hoffmann
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  5. Sinisa Marinkovic
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  6. Jacques Muzart
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Corresponding authors

Correspondence to Boris Estrine or Jean Le Bras.

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Laugel, C., Estrine, B., Le Bras, J. et al. Visible Light-Accelerated Depolymerisation of Starch Under Fenton Conditions and Preparation of Calcium Sequestering Compounds. Catal Lett 144, 1674–1680 (2014). https://doi.org/10.1007/s10562-014-1329-y

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  • DOI: https://doi.org/10.1007/s10562-014-1329-y

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