Abstract
The previously described cyclic pathway method for deposition of atomic metals has been used to create Pd1–6 atomic clusters and Au1–5Pd1 and Au1–4Pd2 bimetallic atomic clusters in polyaniline (PANI). The controlled deposition of predetermined atomic size clusters of metals has been examined by testing the electrochemical oxidation of n-propanol in 1 M NaOH. The oxidation peak currents from the cyclic voltammograms were found to follow the same trend as the changes of the calculated HOMO–LUMO gap energies. The FTIR signature of PANI for these films also followed the calculated trend. This study also looks at the effects of atomic arrangement in the atomic structure on the support matrix of PANI. The results presented here have shown that the cyclic pathway is a versatile method for the atomic deposition of single metal, bimetallic, or even trimetallic atomic clusters in PANI.
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Jonke AP, Josowicz M, Janata J (2012) J Electrochem Soc 159:P40
Jonke AP, Josowicz M, Janata J, Engelhard MH (2010) J Electrochem Soc 157:P83
Jonke AP, Josowicz M, Janata J (2011) J Electrochem Soc 158:E147
Moghaddam RB, Pickup PG (2011) Electrochim Acta 56:7666
Choudary BM, Roy M, Roy S, Kantam ML, Sreedhar B, Kumar KV (2006) Adv Synth Catal 348:1734
Islam RU, Witcomb MJ, van der Lingen E, Scurrell MS, Van Otterlo W, Mallick K (2011) J Organomet Chem 696:2206
Drelinkiewicz A, Hasik M, Kloc M (2000) Catal Lett 64:41
Drelinkiewicza A, Waksmundzka A, Makowski W, Sobczak JW, Krol A, Zieba A (2004) Catal Lett 94:143
Pandey RK, Lakshminarayanan V (2009) J Phys Chem C 113:21596
Amaya T, Saio D, Hirao T (2007) Tetrahedron Lett 48:2729
Liu HP, Ye JQ, Xu CW, Jiang SP, Tong YX (2008) J Power Sources 177:67
Wang DY, Liu JP, Wu ZY, Zhang JH, Su YZ, Liu ZL, Xu CW (2009) Int J Electrochem Sci 4:1672
Ye JQ, Liu HP, Xu CW, Jiang SP, Tong YX (2007) Electrochem Commun 9:2760
Hakkinen H, Landman U (2000) Phys Rev B 62:R2287
Zanti G, Peeters D (2010) J Phys Chem A 114:10345
Dimitratos N, Villa A, Wang D, Porta F, Su DS, Prati L (2006) J Catal 244:113
Hou WB, Dehm NA, Scott RWJ (2008) J Catal 253:22
Bianchi CL, Canton P, Dimitratos N, Porta F, Prati L (2005) Catal Today 102:203
Landon P, Collier PJ, Carley AF, Chadwick D, Papworth AJ, Burrows A, Kiely CJ, Hutchings GJ (2003) PCCP 5:1917
Smith JA, Josowicz M, Janata J (2005) PCCP 7:3614
Denuault G, Milhano C, Pletcher D (2005) PCCP 7:3545
Bolzan AE (1995) J Electroanal Chem 380:127
Chi K-W, Hwang HY, Park JY, Lee CW (2009) Synth Met 159:26
Higuchi M, Ikeda I, Hirao T (1997) J Org Chem 62:1072
Lee CW, Hwang HY, Jeong HM, Yoon UC, Chi K-W (2009) Synth Met 159:1820
Nava P, Sierka M, Ahlrichs R (2003) PCCP 5:3372
Kang ET, Neoh KG, Tan KL (1998) Prog Polym Sci 23:277
Ai-Jie M, Xiao-Yu K, Gang C, Ya-Ru Z, Yan-Fang L, Peng L, Chi Z (2011) Mol Phys 109:1485
Guo JJ, Yang JX, Die D (2005) Phys B Condens Matter 367:158
Acknowledgments
The ICP-MS contributions to the submitted manuscript were performed by UChicago Argonne, LLC, Operator of Argonne National Laboratory (‘‘Argonne’’). Argonne, a US Department of Energy Office of Science laboratory, is operated under Contract No. DE-AC02-06CH11357. Funding provided for this work from the Georgia Research Alliance is greatly appreciated.
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Jonke, A.P., Steeb, J.L., Josowicz, M. et al. Atomic Clusters of Pd and AuNPdM in Polyaniline. Catal Lett 143, 531–538 (2013). https://doi.org/10.1007/s10562-013-1005-7
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DOI: https://doi.org/10.1007/s10562-013-1005-7