Abstract
The heteropolyanion-based ionic liquid (IL) material [MIMPS]3PW12O40, propane sulfoacid-functionalized imidazolium salt of phosphotungstate, was used as a solid catalyst for liquid-phase Beckmann rearrangements of ketoximes in the presence of zinc chloride. The resultant liquid–solid biphasic rearrangement reaction of cyclohexanone oxime shows a high yield 83 % with good recyclability. The testing of control catalysts, reaction conditions, oxime substrates, and recycling property were carried out and the results are discussed.
Graphical Abstract
The heteropolyanion-based ionic liquid (IL) material [MIMPS]3PW12O40, propane sulfoacid-functionalized imidazolium salt of phosphotungstate, was used as a solid catalyst for liquid-phase Beckmann rearrangements of ketoximes in the presence of zinc chloride. The resultant liquid-solid biphasic rearrangement reaction of cyclohexanone oxime shows a high yield 83% with good recyclability. The testing of control catalysts, reaction conditions, oxime substrates, and recycling property were carried out, and the results are discussed.
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The authors thank greatly the National Natural Science Foundation of China (No. 21136005).
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Zhang, X., Mao, D., Leng, Y. et al. Heterogeneous Beckmann Rearrangements Catalyzed by a Sulfonated Imidazolium Salt of Phosphotungstate. Catal Lett 143, 193–199 (2013). https://doi.org/10.1007/s10562-012-0939-5
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DOI: https://doi.org/10.1007/s10562-012-0939-5