Cycloaddition of CO2 to Epoxides Using a Highly Active Co(III) Complex of Tetraamidomacrocyclic Ligand
- First Online:
- Cite this article as:
- Ghosh, A., Ramidi, P., Pulla, S. et al. Catal Lett (2010) 137: 1. doi:10.1007/s10562-010-0325-0
- 662 Downloads
Synthesis of various cyclic carbonates with yield up to 100% and turn over frequency (TOF) of 351 h−1 using CO2 and epoxides and a cobalt (III) complex of tetraamidomacrocyclic ligand is described. The catalyst was characterized by single crystal X-ray crystallography. A study of reaction conditions indicates that 2 MPa pressure of CO2 without any co-solvent is sufficient to achieve the desired product.