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Liquid Phase Oxidation of Glycerol Using a Single Phase (Au–Pd) Alloy Supported on Activated Carbon: Effect of Reaction Conditions

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Abstract

The liquid phase oxidation of glycerol has been studied over gold–palladium nanoparticles supported on activated carbon and synthesized by using a one-protocol synthesis. The effect of pressure, catalyst amount and base has been examined by using an autoclave reactor with molecular oxygen as oxidant at mild conditions. By choosing the appropriate reaction conditions control of selectivity could be possible, whereas activity is strongly dependent on catalyst amount and concentration of base.

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Author notes

  1. Nikolaos Dimitratos

    Present address: School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, UK

Authors and Affiliations

  1. Dipartimento CIMA “L.Malatesta”, Università di Milano, via Venezian 21, 20133, Milan, Italy

    Nikolaos Dimitratos, Alberto Villa & Laura Prati

Authors
  1. Nikolaos Dimitratos
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  2. Alberto Villa
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  3. Laura Prati
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Correspondence to Laura Prati.

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Dimitratos, N., Villa, A. & Prati, L. Liquid Phase Oxidation of Glycerol Using a Single Phase (Au–Pd) Alloy Supported on Activated Carbon: Effect of Reaction Conditions. Catal Lett 133, 334–340 (2009). https://doi.org/10.1007/s10562-009-0192-8

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  • DOI: https://doi.org/10.1007/s10562-009-0192-8

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