Skip to main content
Log in

A Novel Method for Preparing V-doped Titanium Dioxide Thin Film Photocatalysts with High Photocatalytic Activity Under Visible Light Irradiation

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

The liquid phase deposition (LPD) method was successfully used for preparing V-doped TiO2 thin film photocatalysts. In this simple and easily-controlled process, V-doped anatase TiO2 thin films were directly deposited on a soda lime glass substrate placed in an aqueous solution containing Ti- and V-fluoro complex ions, followed by annealing. The thin films were analyzed by XRD, XPS, UV-vis. V4+ ions were introduced into the lattice of TiO2 through in-situ substituting Ti4+. The absorption edge of V-doped TiO2 films shifted to visible light region. The highly efficient photocatalytic activity was verified by the decomposition of methylene blue under visible light irradiation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Carp O, Huisman CL, Reller A (2004) Prog Solid State Chem 32:33

    Article  CAS  Google Scholar 

  2. Fujishima A, Rao TN, Tryk DA (2000) J Photochem Photobiol C: Photochem Rev 1:1

    Article  CAS  Google Scholar 

  3. Fujishima A, Honda K (1972) Nature 238:37

    Article  CAS  Google Scholar 

  4. Khan SUM, Al-Shahry M, Ingler WB Jr (2002) Science 297:2243

    Article  CAS  Google Scholar 

  5. Asahi R, Morikawa T, Ohwaki T, Aoki K, Taga Y (2001) Science 293:269

    Article  CAS  Google Scholar 

  6. Gole JL, Stout JD, Burda C, Lou Y, Chen X (2004) J Phys Chem B 108:1230

    Article  CAS  Google Scholar 

  7. Umebayashi T, Yamaki T, Itoh H, Asai K (2002) J Phys Chem Solids 63:1909

    Article  CAS  Google Scholar 

  8. Dvoranová D, Brezová V, Mazúr M, Malati MA (2002) Appl Catal B- Environ 37:91

    Article  Google Scholar 

  9. Yamashita H, Harada M, Misaka J, Takeuchi M, Ikeue K, Anpo M (2002) J Photochem Photobiol A: Chem 148:257

    Article  CAS  Google Scholar 

  10. Zhou JK, Takeuchi M, Zhao XS, Ray AK, Anpo M (2006) Catal Lett 106:67

    Article  CAS  Google Scholar 

  11. Zhao GL, Kozuka H, Lin H, Yoko T (1999) Thin Solid Films 339:123

    Article  CAS  Google Scholar 

  12. Iketani K, Sun RD, Toki M, Hirota K, Yamaguchi O (2004) Mat Sci Eng B-solid 108:187

    Article  Google Scholar 

  13. Jimmy CY, Jun L, Raymund WM, Wok K (1997) J Photochem Photobiol A: Chem 111:199

    Article  Google Scholar 

  14. Klosek S, Raftry D (2001) J Phys Chem B 105:2815

    Article  CAS  Google Scholar 

  15. Forzatti P, Tronconi E, Busca G, Tittarelli P (1986) Catal Today 1:209

    Article  Google Scholar 

  16. Briand LE, Bonette RD, Sanchez MA, Thomas HJ (1996) Catal Today 32:205

    Article  CAS  Google Scholar 

  17. Kawahara H, Honda H (1984) Japanese patent 59141441 A (Nippon Sheet Glass), August 14

  18. Sakai Y, Norimatsu H, Saito Y, Inomata H, Mizuno T (2001) Thin Solid Films 392:294

    Article  CAS  Google Scholar 

  19. Masuda Y, Seo W-S, Koumoto K (2004) Solid State Ionics 172:283

    Article  CAS  Google Scholar 

  20. Deki S, Aoi Y, Miyake Y, Gotoh A, Kajinami A (1996) Mater Res Bull 31:1399

    Article  CAS  Google Scholar 

  21. Deki S, Kuratani K, Uemura M, Akamatsu K, Mizuhata M, Kajinami A (2004) Thin Solid Films 460:83

    Article  CAS  Google Scholar 

  22. Jeffrey C-SW, Chen C-H (2004) J Photochem Photobiol A: Chem 163:509

    Article  Google Scholar 

  23. Su C, Hong B-Y, Tseng C-M (2004) Catal Today 96:119

    Article  CAS  Google Scholar 

  24. Shi Y-L, Zhang X-G, Li H-L (2002) Mat Sci Eng A-Struc 333:239

    Article  Google Scholar 

  25. Gopal M, Chan WJM, Jonghe LCD (1997) J Mater Sci 32:6001

    Article  CAS  Google Scholar 

  26. Davidson A, Che M (1992) J Phys Chem 96:9909

    Article  CAS  Google Scholar 

  27. Larrubia MA, Busca G (2001) Mater Chem Phys 72:337

    Article  CAS  Google Scholar 

  28. Ares MAB, Alemany LJ, Jime’nez MC, Larrubia MA, Delgado F, Granados ML, Martı’nez-Arias A, Blasco JM, Fierro JLG (1996) J Solid State Chem 124:69

    Article  Google Scholar 

  29. Trifiro F (1998) Catal Today 41:21

    Article  CAS  Google Scholar 

  30. Babelon P, Dequiedt AS, Moste’fa-Sba H, Bourgeois S, Sibillot P, Sacilotti M (1998) Thin Solid Films 322:63

    Article  CAS  Google Scholar 

  31. Atashbar MZ, Sun HT, Gong B, Wlodarski W, Lamb R (1998) Thin Solid Films 326:238

    Article  CAS  Google Scholar 

  32. Rahmana MM, Krishna KM, Soga T, Jimbo T, Umeno M (1999) J Phys Chem Solids 60:201

    Article  Google Scholar 

  33. Kumar S, Fedorov AG, Gole JL (2005) Appl Catal B- Environ 57:93

    Article  CAS  Google Scholar 

  34. Chen J, Ollis DF, Rulkens WH, Bruning H (1999) Wat Res 33:1173

    Article  CAS  Google Scholar 

  35. Houas A, Lachheb H, Ksibi M, Elaloui E, Guillard C, Herrmann J-M (2001) Appl Catal B- Environ 31:145

    Article  CAS  Google Scholar 

  36. Davydov L, Reddy EP, France P, Smirniotis PG (2001) J Catal 203:157

    Article  CAS  Google Scholar 

  37. Lia D, Haneda H, Hishita S, Ohashi N, Labhsetwar NK (2005) J Fluorine Chem 126:69

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to De-En Gu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gu, DE., Yang, BC. & Hu, YD. A Novel Method for Preparing V-doped Titanium Dioxide Thin Film Photocatalysts with High Photocatalytic Activity Under Visible Light Irradiation. Catal Lett 118, 254–259 (2007). https://doi.org/10.1007/s10562-007-9179-5

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-007-9179-5

Keywords

Navigation