It is established that carbonate dissolution kinetics have diffusion and kinetic control, i.e., chemical reaction rate determines the transfer of calcium and carbonate ions into solution and diffusion processes determine the removal of ions into the depth of solution. Kinetics of calcite and siderite dissolution in hydrochloric acid solution in relation to medium pH are studied. Orders of dissolution reaction rate with respect to hydrogen ions n(H+) = 0.6±0.1 are calculated.
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Research was carried out with financial support from the Russian Foundation for Basic Research within the scope of scientific projects Nos. 14-03-00265_a and 14-03-31347_mol_a.
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Translated from Khimicheskoe i Neftegazovoe Mashinostroenie, No. 9, pp. 38–40, September, 2014.
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Artamonova, I.V., Gorichev, I.G. & Godunov, E.B. Study of Calcium and Iron Carbonate Dissolution Kinetics in Order to Resolve Corrosion Problems in Carbonate Solutions. Chem Petrol Eng 50, 605–609 (2015). https://doi.org/10.1007/s10556-014-9949-z
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DOI: https://doi.org/10.1007/s10556-014-9949-z