A kinetic analysis is presented for a proposed scheme for sulfone production by the oxidation of petroleum sulfoxides by the action of hydrogen peroxide using a molybdenum (VI) oxide catalyst. Theoretical calculations and experimental data indicate that the sulfone concentration in the initial stages of the reaction depends linearly on the square of the elapsed reaction time. The effective activation energy of this reaction was found to be E act = (31 ± 7) kJ/mole.
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This work was carried in the framework of a State Project of the Ministry of Education and Science of the Russian Federation on Scientific Research.
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Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 1, pp. 17 – 19, January – February, 2017.
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Borisov, I.M., Faizrakhmanov, I.S., Alekhina, I.E. et al. Kinetics of Sulfone Accumulation in the Catalyzed Peroxode Oxidation of Petroleum Sulfoxides. Chem Technol Fuels Oils 53, 23–28 (2017). https://doi.org/10.1007/s10553-017-0777-7
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DOI: https://doi.org/10.1007/s10553-017-0777-7