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Renewable β-myrcene polymerization initiated by lutetium alkyl complexes ligated by imidophosphonamido ligand

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Abstract

β-imidophosphonamido ligated lutetium alkyl complex (NPNDipp)Lu(CH2SiMe3)2(THF) (NPNDipp = Ph2P(NC6H3 iPr2-2,6)2) with the activation of AliBu3 and [Ph3C][B(C6F5)4] exhibited high catalytic activity, medium syndio-(rr = 66%) but remarkably high 3,4-regioselectivity for the polymerization of β-myrcene (MY). In sharp contrast, high isotactic 3,4-polymyrcene (PMY) (mm = 95%) was obtained by the precursor (NPNEt)Lu(CH2SiMe3)2(THF) (NPNEt = PPh2(NC6H3 iPr2-2,6)(NC6H4-Et-2)) with less bulky substituents on the N-aryl ring.

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Authors and Affiliations

  1. Key Laboratory of Automobile Materials of Ministry of Education, Department of Materials Science and Engineering, Jilin University, Changchun, 130022, China

    Bo Liu, Chun-ling Zhang & Guang-ping Sun  (孙广平)

  2. Changchun Vocational Institute of Technology, Changchun, 130000, China

    Bao-yu Han

  3. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China

    Shi-hui Li  (李世辉) & Dong-mei Cui  (崔冬梅)

Authors
  1. Bo Liu
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  2. Bao-yu Han
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  3. Chun-ling Zhang
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  4. Shi-hui Li  (李世辉)
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  5. Guang-ping Sun  (孙广平)
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  6. Dong-mei Cui  (崔冬梅)
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Corresponding authors

Correspondence to Shi-hui Li  (李世辉), Guang-ping Sun  (孙广平) or Dong-mei Cui  (崔冬梅).

Additional information

This work was financially supported by the National Natural Science Foundation of China (Nos. 21104074 and 51321062).

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Liu, B., Han, By., Zhang, Cl. et al. Renewable β-myrcene polymerization initiated by lutetium alkyl complexes ligated by imidophosphonamido ligand. Chin J Polym Sci 33, 792–796 (2015). https://doi.org/10.1007/s10118-015-1629-8

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  • DOI: https://doi.org/10.1007/s10118-015-1629-8

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