Skip to main content
Log in

Preparation and characterization of ferric-impregnated granular ceramics (FGCs) for phosphorus removal from aqueous solution

  • Original Paper
  • Published:
Clean Technologies and Environmental Policy Aims and scope Submit manuscript

Abstract

In the present study, the ferric-impregnated granular ceramic (FGC) adsorbents were developed for the removal of phosphorus from aqueous solution. BET, SEM, and EDS were used to characterize the physical and chemical attributes (particle size, pore size and distribution, surface roughness, and chemical composition) of FGCs. Phosphorus adsorption characteristics were studied in a static batch system with respect to changes in contact time, initial phosphorus concentration, pH of solution, and temperature. The adsorption process was observed to follow a pseudo-first-order kinetic model, taking about 36 h to attain equilibrium. Phosphorus adsorption was found to be pH dependent and the maximum removal was obtained at pH 7.0–9.0. The experimental data denoted that the Langmuir isotherm model gave a more satisfactory fit for phosphorus removal than the Freundlich isotherm model. Results suggested that the novel adsorbent of FGCs had a good potential in remediation of phosphorus removal in aqueous solutions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  • Blaney LM, Cinar S, Sengupta AK (2007) Hybrid anion exchanger for trace phosphate removal from water and wastewater. Water Res 41:1603–1613

    Article  CAS  Google Scholar 

  • Blindow I, Hargeby A, Andersson G (2002) Seasonal changes of mechanisms maintaining clear water in a shallow lake with abundant Chara vegetation. Aquat Bot 72:315–334

    Article  Google Scholar 

  • Borgnino L, Avena MJ, De Pauli CP (2009) Synthesis and characterization of Fe(III)—montmorillonites for phosphate adsorption. Colloid Surf A 341:46–52

    Article  CAS  Google Scholar 

  • Boyer TH, Persaud A, Banerjee P, Palomino P (2011) Comparison of low-cost and engineered materials for phosphorus removal from organic-rich surface water. Water Res 45:4803–4814

    Article  CAS  Google Scholar 

  • Chen N, Feng CP, Zhang ZY, Liu RP, Gao Y, Li M, Sugiura N (2012) Preparation and characterization of lanthanum (III) loaded granular ceramic for phosphorus from aqueous solution. J Taiwan Inst Chem Eng. doi:10.1016/j.jtice.2012.04.003

    Google Scholar 

  • Cheng X, Huang XR, Wang XZ, Zhao BQ, Chen AY, Sun DZ (2009) Phosphate adsorption from sewage sludge filtrate using zinc-aluminum layered double hydroxides. J Hazard Mater 169:958–964

    Article  CAS  Google Scholar 

  • Chitrakar R, Tezuka S, Sonoda A, Sakane K, Ooi K, Hirotsu T (2005) Adsorption of phosphate from seawater on calcined MgMn-layered double hydroxides. J Colloid Interface Sci 290:45–51

    Article  CAS  Google Scholar 

  • Chutia P, Kato S, Kojima T, Satokawa S (2009) Arsenic adsorption from aqueous solution on synthetic zeolites. J Hazard Mater 162:440–447

    Article  CAS  Google Scholar 

  • Das J, Patra BS, Baliarsingh N, Parida KM (2006) Adsorption of phosphate by layered double hydroxides in aqueous solutions. Appl Clay Sci 32:252–260

    Article  CAS  Google Scholar 

  • De-Bashana LE, Bashan Y (2004) Recent advances in removing phosphorus from wastewater and its future use as fertilizer (1997–2003). Water Res 38:4222–4246

    Article  Google Scholar 

  • Ding W, Huang X, Zhang L (2003) Removal of phosphorus from aqueous solution by lanthanum hydrate. Environ Sci 24:110–113

    CAS  Google Scholar 

  • Freundlich HMF (1906) Über die adsorption in losungen. Z Phy Chem. 57 A: 385–470

    Google Scholar 

  • Grzmil B, Wronkowski J (2006) Removal of phosphates and fluorides from industrial wastewater. Desalination 189:261–268

    Article  CAS  Google Scholar 

  • Haghseresht F, Wang SB, Do DD (2009) A novel lanthanum-modified bentonite, Phoslock, for phosphate removal from wastewaters. Appl Clay Sci 46:369–375

    Article  CAS  Google Scholar 

  • Ho YS, Mckay G (1999) Pseudo-second order model for sorption process. Process Biochem 34:451–465

    Article  CAS  Google Scholar 

  • Huang W, Wang S, Zhu Z, Li L, Yao X, Rudolph V, Haghseresht F (2008) Phosphate removal from wastewater using red mud. J Hazard Mater 158:35–42

    Article  CAS  Google Scholar 

  • Kuzawa K, Jung YJ, Kiso Y, Yamada T, Nagai M, Lee TG (2006) Phosphate removal and recovery with a synthetic hydrotalcite as an adsorbent. Chemosphere 62:45–52

    Article  CAS  Google Scholar 

  • Lagergren S, Svenska K (1898) About the theory of so called adsorption of soluble substances. K Sven Vetenskapsad Handl 24(4):1–39

    Google Scholar 

  • Langmuir I (1916) The constitution and fundamental properties of solids and liquids. J Am Chem Soc 38:2221–2295

    Article  CAS  Google Scholar 

  • Luengo C, Brigante M, Antelo J, Avena M (2006) Kinetics of phosphate adsorption on goethite: comparing batch adsorption and ATR-IR measurements. J Colloid Interface Sci 300:511–518

    Article  CAS  Google Scholar 

  • Morse GK, Brett SW, Guy JA, Lester JN (1998) Review: phosphorus removal and recovery technologies. Sci Total Environ 212:69–81

    Article  CAS  Google Scholar 

  • Nowack B, Stone AT (2006) Competitive adsorption of phosphate and phosphonates onto goethite. Water Res 40:2201–2209

    Article  CAS  Google Scholar 

  • Ouvrard S, Donato PD, Simonnot MO, Begin S, Ghanbaja J, Alnot M, Duval YB, Lhote F, Barres O, Sardin M (2005) Natural manganese oxide: combined analytical approach for solid characterization and arsenic retention. Geochimica Cosmochimica Acta 69:2715–2724

    Article  CAS  Google Scholar 

  • Peleka EN, Deliyanni EA (2009) Adsorptive removal of phosphates from aqueous solutions. Desalination 245:357–371

    Article  CAS  Google Scholar 

  • Ramesh C, Satoko T, Akinari S, Kohji S, Kenta O, Takahiro H (2006) Selective adsorption of phosphate from seawater and wastewater by amorphous zirconium hydroxide. J Colloid Interface Sci 297:426–433

    Article  Google Scholar 

  • Roques H, Nugroho-Jeudy L, Lebugle A (1991) Phosphorus removal from wastewater by half-burned dolomite. Water Res 25:959–965

    Article  CAS  Google Scholar 

  • Salah B, Moussa A (2011) Adsorption of phosphate ions onto low cost Aleppo pine adsorbent. Desalination 275:231–236

    Article  Google Scholar 

  • Shin EW, Han JS (2004) Phosphate adsorption on aluminum-impregnated mesoporous silicates: surface structure and behavior of adsorbents. Environ Sci Technol 38:912–917

    Article  CAS  Google Scholar 

  • Smiciklas ID, Milonjic SK, Pfendt P, Raicevic S (2000) The point of zero charge and sorption of cadmium (II) and strontium (II) ions on synthetic hydroxyapatite. Sep Purif Technol 18:185–194

    Article  CAS  Google Scholar 

  • Tian SL, Jiang PX, Ning P, Su YH (2009) Enhanced adsorption removal of phosphate from water by mixed lanthanum/aluminum pillared montmorillonite. Chem Eng J 151:141–148

    Article  CAS  Google Scholar 

  • Wang SR, Jin XC, Panf Y, Zhao HC, Zhou XN (2005) The study of the effect of pH on phosphate sorption by different trophic lake sediments. J Colloid Interface Sci 285:448–457

    Article  CAS  Google Scholar 

  • Water and Wastewater Monitoring Analysis Method (2002) 4th edn, China Environmental Science Press, China 4: 246–248

  • Xiong J, He Z, Mahmood Q, Liu D, Yang X, Islam E (2008) Phosphate removal from solution using steel slag through magnetic separation. J Hazard Mater 152:211–215

    Article  CAS  Google Scholar 

  • Zhang JD, Shen ZM, Wenpo S, Mei ZJ, Wang WH (2011) Adsorption behavior of phosphate on lanthanum (III)-coordinated diamino-functionalized 3D hybrid mesoporous silicates material. J Hazard Mater 186:76–83

    Article  CAS  Google Scholar 

  • Zhong B, Stanforth R, Wu S, Chen JP (2007) Proton interaction in phosphate adsorption onto goethite. J Colloid Interface Sci 308:40–48

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors thank the Fundamental Research Funds for the Central Universities, Water Pollution Control and Treatment Key Projects (2009ZX07 102-002-01), and the National Natural Science Foundation (No. 31140082) for the financial support of this work.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Chuanping Feng.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chen, N., Feng, C., Yang, J. et al. Preparation and characterization of ferric-impregnated granular ceramics (FGCs) for phosphorus removal from aqueous solution. Clean Techn Environ Policy 15, 375–382 (2013). https://doi.org/10.1007/s10098-012-0527-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10098-012-0527-9

Keywords

Navigation