Abstract
Lead lithium titanium oxide with the composition PbLi2Ti6O14 has been successfully synthesized by the rheological phase reaction method and exhibited excellent electrochemical properties as an anode material for lithium ion batteries. The results show that PbLi2Ti6O14 with a three-dimensional network could reversibly accommodate about four lithium ions (146.4 mAh g−1) per unit formula along with the partial reduction of Ti4+ to Ti3+, and the multiple steps of lithium insertion during the cycling process were explained from crystallographic view point. Moreover, when the load current density was increased from 100 to 200, to 400, and then to 800 mA g−1, the corresponding charge capacity was 134.8, 119.6, 103.7, and 86.3 mAh g−1, respectively, and the capacity recovered to 128.7 mAh g−1 if the current density was returned to 100 mA g−1. Thus, the PbLi2Ti6O14, with certain specific capacity, excellent cycling performance and rate capability, can be used as a promising anode material for lithium ion battery applications.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Etacheri V, Marom R, Elazari R, Salitra G, Aurbach D (2011) Energy Environ Sci 4:324–3262
Zhu GN, Wang YG, Xia YY (2012) Energy Environ Sci 5:6652–6667
Yoshio M, Wang HY, Fukuda K, Umeno T, Abe T, Ogumi Z (2004) J Mater Chem 14:1754–1758
Borghols WJH, Wagemaker M, Lafont U, Kelder EM, Mulder FM (2008) Chem Mater 20:2949–2955
Wang J, Polleux J, Lim J, Dunn B (2007) J Phys Chem C 111:14925–14931
Hu H, Yu L, Gao XH, Lin Z, Lou XW (2015) Energy Environ Sci 8:1480–1483
Mukai K, Kato Y, Nakano H (2014) J Phys Chem C 118:2992–2999
Liao JY, Chabot V, Gu M, Wang CM, Xiao XC, Chen ZW (2014) Nano Energy 9:383–391
Belharouak I, Amine K (2003) Electrochem Commun 5:435–438
Yin SY, Song L, Wang XY, Huang YH, Zhang KL, Zhang YX (2009) Electrochem Commun 11:1251–1254
Dambournet D, Belharouak L, Amine K (2010) Inorg Chem 9:2822–2826
Liu JH, Wu BR, Wang XQ, Wang S, Gao Y, Wu NN, Yang N, Chen ZZ (2016) J Power Sources 301:362–368
Liu JH, Li YN, Wang XQ, Gao Y, Wu NN, Wu BR (2013) J Alloys Compd 581:236–240
Li HS, Shen LF, Ding B, Pang G, Dou H, Zhang XG (2015) Nano Energy 13:18–27
Lin XT, Wang PF, Li P, Yu HX, Qian SS, Shui M, Wang DJ, Long NB, Shu J (2015) Electrochim Acta 186:24–33
Lin XT, Qian SS, Yu HX, Yan L, Li P, Wu YY, Long NB, Shui M, Shu J (2016) ACS Sustain Chem Eng 4:4859–4867
Wu KQ, Shu J, Lin XT, Shao LY, Li P, Shui M, Lao MM, Long NB, Wang DJ (2015) J Power Sources 275:419–428
Ghosh S, Kee Y, Okada S, Barpanda P (2015) J Power Sources 296:276–281
Koseva I, Chaminade JP, Gravereau P, Pechev S, Peshev P (2005) J Alloys Compd 389:47–54
Qian SS, Yu HX, Yan I, Li P, Lin XT, Wu YY, Long NB, Shui M, Shu J (2016) Electrochim Acta 212:950–957
Li P, Qian SS, Yu HX, Yan L, Lin XT, Yang K, Long NB, Shui M, Shu J (2016) J Power Sources 330:45–54
Chen W, Liang HF, Shao LY, Shu J, Wang ZC (2015) Electrochim Acta 152:187–194
Acknowledgements
This work was supported by the Natural Science Grant of China (No. 21476063) and the Scientific Research Project of Hubei Provincial Department of Education (B2014166).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Sun, X., Yin, S. & Feng, C. Synthesis and electrochemical properties of PbLi2Ti6O14 for lithium ion battery applications. J Solid State Electrochem 21, 1625–1630 (2017). https://doi.org/10.1007/s10008-017-3531-5
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-017-3531-5