Abstract
A review is presented of the photoelectrochemical and Mott–Schottky analysis for the passive film formed on Ni and its alloys, and also of its application to clarifying the role of chloride ion and solution temperature in their corrosion behaviors. Photocurrent spectra for the passive film of Ni and its alloys, measured by the continuous illumination technique, can be resolved into spectral components, each of which originated from each compound comprising the passive film such as inner NiO and outer Ni(OH)2. The composition, structure, and electronic band structure of the passive films were characterized by comparing the band gap energy and the shape and peak position in the photocurrent spectra for the films with those for the thermally grown oxide. Mott–Schottky analysis revealed that the concentration of cation vacancy in p-type passive film of Ni is significantly increased either with addition of chloride ion or with raising solution temperature The significant increase in the concentration of cation vacancy is found to be main reason for the Cl− inducing passivity breakdown and also for the increase in corrosion rate with solution temperature. These experimental results are well corresponded to the role of Cl− in the passivity breakdown proposed by the point defect model.
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References
Wilhelm SM, Hackerman N (1981) J Electrochem Soc 128:1668–1674
Sunseri C, Piazza S, Di Quarto F (1995) Mater Sci Forum 185–188:435–446
Fujimoto S, Tsuchiya H, Sakamoto M, Shibata T, Asami K (2002) 201st Meeting of the Electrochemical Society, Philadelphia, Pennsylvania, 12-17 May 278
Jang H, Park C, Kwon H (2005) Electrochim Acta 50:3503–3508
Lim AS, Atrens A (1992) Appl Phys A 54:343–349
Jabs T, Borthen P, Strehblow HH (1997) J Electrochem Soc 144:1231–1243
Boudin S, Vignes JL, Lorang G, Da Cunha BM, Blondiaux G, Mikhailov SM, Jacobs JP, Brongersma HH (1994) Surf Interface Anal 22:462–466
Bojinov M, Fabricius G, Kinnunen P, Laitinen T, Mäkelä K, Saario T, Sundholm G (2001) J Electroanal Chem 504:29–44
Machet A, Galtayries A, Marcus P, Combrade P, Jolivet P (2002) Scott P Surf. Interface Anal 34:197–200
Machet A, Galtayries A, Zanna S, Klein L, Maurice V, Jolivet P, Foucault M, Combrade P, Scott P, Marcus P (2004) Electrochim Acta 49:3957–3964
Terachi T, Totsuka N, Yamada T, Nakagawa T, Deguchi H, Horiuchi M, Oshitani M (2003) J Nucl Sci Technol 40:509–516
Montemor MF, Ferreira MGS, Walls M, Rondot B, Da Cunha BM (2003) Corrosion 59:11–21
Dutta RS, Lobo A, Purandare R, Kulkarni SK, Dey GK (2002) Metall Mater Trans A 33A:1437–1447
Jang H, Oh KN, Ahn S, Kwon H (2014) Met Mater Int 20:277–283
Paik WK, Szklarska-Smialowska Z (1980) Surf Sci 96:401–412
Scherer J, Ocko BM, Magnussen OM (2003) Electrochim Acta 48:1169–1191
Marcus P, Herbelin JM (1993) Corros Sci 34:1123–1145
Ohtsuka T, Schoner K, Heusler KE (1978) J Electroanal Chem 93:171–182
Sato N, Kudo K (1974) Electrochim Acta 19:461–470
Chao CY, Szklarska-Smialowska Z, Macdonald DD (1982) J Electroanal Chem 131:289–297
MacDougall B, Cohen MJ (1974) Electrochem Soc 121:1152–1159
MacDougall B, Cohen M (1976) J Electrochem Soc 123:191–197
Maurice V, Yang WP, Marcus P (1996) J Electrochem Soc 143:1182–1200
Haupt S, Strehblow HH (1995) Corros Sci 37:43–54
Oblonsky LJ, Ryan MP, Isaacs HS (1998) J Electrochem Soc 145:1922–1932
Kirchheim R, Heine B, Fischmeister H, Hofmann S, Knote H, Stolz U (1989) Corros Sci 29:899–917
Lorang G, Da Cunha BM, Simões AMP, Ferreira MGS (1994) J Electrochem Soc 141:3347–3356
Hakiki NE, Boudin S, Rondot B, Da Cunha BM (1995) Corros Sci 37:1809–1822
Cho E, Kwon H, Macdonald DD (2002) Electrochim Acta 47:1661–1668
Fujimoto S, Chihara O, Shibata T (1998) Mater Sci Forum 289–292:989–996
Sunseri C, Piazza S, Di Paola A, Di Quarto F (1987) J Electrochem Soc 134:2410–2416
Ahn S, Kwon H (2004) Electrochim Acta 49:3347–3353
Kim J, Cho E, Kwon H (2000) Corros Sci 43:1403–1415
Ferreira MGS, Hakiki NE, Goodlet G, Faty S, Simões AMP, Da Cunha BM (2001) Electrochim Acta 46:3767–3776
Di Paola A (1989) Electrochim Acta 34:203–210
Simões AMP, Ferreira MGS, Rondot B, Da Cunha BM (1990) J Electrochem Soc 137:82–87
Gerischer H (1989) Corros Sci 29:257–266
Trabanelli G, Zucchi F, Brunoro G, Bolognesi GP (1972) Thin Solid Films 13:131–142
Myamlin VA, Pleskov YV (1967) Electrochemistry of semiconductors. Plenum, New York
Macdonald DD (1992) J Electrochem Soc 139:3434–3449
Schmuki P, Bohni H (1991) Werkst Korros 42:203–207
Schmuki P, Bohni H (1992) J Electrochem Soc 139:1908–1913
Di Quarto F, Santamaria M (2004) Corros Eng Sci Technol 39:71–81
Sato N (2000) Corros Sci 42:1957–1973
Gärtner WW (1959) Phys Rev 116:84–87
Bube RH (1992) Photoelectronic properties of semiconductors. Cambridge University Press, Cambridge UK
Azumi K, Ohtsuka T, Sato N (1990) Corros Sci 31:715–720
Abrantes LM, Peter LM (1983) J Electroanal Chem 150:593–601
Hara N, Sugimoto K (1988) Jpn J Metal Inst 52:189
Piazza S, Sperandeo M, Sunseri C, Di Quarto F (2004) Corros Sci 46:831–851
Tsuchiya H, Fujimoto S, Shibata T (2004) J Electrochem Soc 151:B39–B44
Kim J, Cho E, Kwon H (2001) Electrochim Acta 47:415–421
Kim D, Ahn S, Kwon H (2006) Thin Solid Films 513:212–216
Jang H, Park C, Kwon H (2010) Met Mater Int 16:247–252
Jang H, Kwon H (2006) Corros Sci Technol 5:141–148
Jang H, Kwon H (2006) J Electroanal Chem 590:120–125
Jang H, Park C, Kwon H (2009) Met Mater Int 15:57–62
Jang H, Kwon H (2007) ECS Trans 3:1–11
Lee S, Cho E, Ahn S, Kwon H (2001) Electrochim Acta 46:2605–2611
Macdonald DD (1999) Pure Appl Chem 71:951–978
Ahn S, Kwon H, Macdonald DD (2005) J Electrochem Soc 152:B482–B490
Lin LF, Chao CY, Macdonald DD (1981) J Electrochem Soc 128:1187–1194
Macdonald DD, Smedley SI (1990) Electrochim Acta 35:1949–1956
Sikora E, Macdonald DD (2002) Electrochim Acta 48:69–77
Macdonald DD, Biaggio SR, Song H (1992) J Electrochem Soc 139:170–17
Park K, Ahn S, Kwon H (2011) Electrochim Acta 56:1662–1669
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Jang, H., Kwon, H. Photoelectrochemical analysis of passive films formed on Ni and its alloys and its application to their corrosion behaviors. J Solid State Electrochem 19, 3427–3438 (2015). https://doi.org/10.1007/s10008-015-2830-y
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DOI: https://doi.org/10.1007/s10008-015-2830-y