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Copolymeric films obtained by electropolymerization of porphyrins and dipyridyl-spacers including Dawson-type polyoxometalates

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Abstract

This paper reports the formation of hybrid polyoxometalate-porphyrin copolymeric films obtained by the electro-oxidation of zinc-β-octaethylporphyrin (ZnOEP) in the presence of a functionalized Dawson-type polyoxometalate bearing two pyridyl groups (POMdbme3,3, Py-POM-Py) which will be compared to the copolymer obtained from ZnOEP and a dipyridyl compound without POM (ibme3,3). The resulting film has been characterized by UV-visible absorption spectroscopy, X-ray photoelectron spectroscopy, and atomic force microscopy. Electrochemical quartz crystal microbalance was employed to investigate the poly-porphyrin-POMs deposition mass.

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References

  1. Long DL, Tsunashima R, Cronin L (2010) Angew Chem Int Ed Engl 49:1736–1758

    Article  CAS  Google Scholar 

  2. Ahmed I, Farha R, Huo ZH, Allaina C, Wang XX, Xu HL, Goldmann M, Hasenknopf B, Ruhlmann L (2013) Electrochim Acta 110:726–734

    Article  CAS  Google Scholar 

  3. Costa-Coquelard C, Schaming D, Lampre I, Ruhlmann L (2008) Appl Catal B Environ 84:835–842

    Article  CAS  Google Scholar 

  4. Proust A, Matt B, Villanneau R, Guillemot G, Gouzerha P, Izzet G (2012) Chem Soc Rev 41:7605–76022

    Article  CAS  Google Scholar 

  5. Long D-L, Burkholder E, Cronin L (2007) Chem Soc Rev 36:105–121

    Article  CAS  Google Scholar 

  6. Proust A, Thouvenot R, Gouzerh P (2008) Chem Commun 1837–1852

  7. Dolbecq A, Dumas E, Mayer CR, Mialane P (2010) Chem Rev 110:6009–6048

    Article  CAS  Google Scholar 

  8. Thorimbert S, Hasenknopf B, Lacôte E (2011) Isr J Chem 51:275–280

    Article  CAS  Google Scholar 

  9. Yokoyama A, Kojima T, Ohkubo K, Shiro M, Fukuzumi S (2011) J Phys Chem A 115:986–997

    Article  CAS  Google Scholar 

  10. Allain C, Favette S, Chamoreau L, Vaissermann J, Ruhlmann L, Hasenknopf B (2008) Eur J Inorg Chem 2008:3433–3441

    Article  Google Scholar 

  11. Falber A, Burton-Pye BP, Radivojevic I, Todaro L, Saleh R, Francesconi LC, Drain CM (2009) Eur J Inorg Chem 2009:2459–2466

    Article  Google Scholar 

  12. Schaming D, Costa-Coquelard C, Lampre I, Sorgues S, Erard M, Liu X, Liu J, Sun L, Canny J, Thouvenot R, Ruhlmann L (2010) Inorg Chim Acta 363:2185–2192

    Article  CAS  Google Scholar 

  13. Kang J, Xu B, Peng Z, Zhu XD, Wei YG, Powell DR (2005) Angew Chem Int Ed 44:6902–6905

    Article  CAS  Google Scholar 

  14. Stark JL, Young VG, Maatta EA (1995) Angew Chem Int Ed 34:2547–2548

    Article  CAS  Google Scholar 

  15. Kang J, Nelson JA, Lu M, Xie BH, Peng ZH, Powell DR (2004) Inorg Chem 43:6408–6413

    Article  CAS  Google Scholar 

  16. Odobel F, Séverac M, Pellegrin Y, Blart E, Fosse C, Cannizzo C, Mayer CR, Elliott KJ, Harriman A (2009) Chem Eur J 15:3130–3138

    Article  CAS  Google Scholar 

  17. Matt B, Coudret C, Viala C, Jouvenot D, Loiseau F, Izzet G, Proust A (2011) Inorg Chem 50:7761–7768

    Article  CAS  Google Scholar 

  18. Gao J, Liu X, Liu Y, Lingling Y, Feng YH, Chen HY, Li YX, Rakesh G, Huan CHA, Sum TC, Zhao Y, Zhang QH (2012) Dalton Trans 41:12185–12191

    Article  CAS  Google Scholar 

  19. Matt B, Moussa J, Chamoreau L-M, Afonso C, Proust A, Amouri H, Izzet G (2012) Organometallics 31:35–38

    Article  CAS  Google Scholar 

  20. Elliott KJ, Harriman A, Le Pleux L, Afonso C, Proust A, Amouri H, Izzet G (2009) Phys Chem Chem Phys 11:8767–8773

    Article  CAS  Google Scholar 

  21. Araghi M, Mirkhani V, Moghadam M, Tangestaninejad S, Baltorket IM (2012) Dalton Trans 41:3087–3094

    Article  CAS  Google Scholar 

  22. Araghi M, Mirkhani V, Moghadam M, Tangestaninejad S, Baltorket IM (2012) Dalton Trans 41:11745–11752

    Article  CAS  Google Scholar 

  23. Allain C, Schaming D, Karakostas N, Erard M, Gisselbrecht JP, Sorgues S, Lampre L, Ruhlmann L, Hasenknopf B (2013) Dalton Trans 42:2745–2754

    Article  CAS  Google Scholar 

  24. Schaming D, Allain C, Farha R, Goldmann M, Lobstein S, Giraudeau A, Hasenknopf B, Ruhlmann L (2010) Langmuir 26:5101–5109

    Article  CAS  Google Scholar 

  25. Azcarate I, Ahmed I, Farha R, Goldmann M, Wang XX, Xu HL, Hasenknopf B, Lacôte E, Ruhlmann L (2013) Dalton Trans 42:12688–12698

    Article  CAS  Google Scholar 

  26. Ruhlmann L, Schulz A, Giraudeau A, Messerschmidt C, Fuhrhop JH (1999) J Am Chem Soc 121:6664–6667

    Article  CAS  Google Scholar 

  27. Ruhlmann L, Hao J, Ping Z, Giraudeau A (2008) J Electroanal Chem 621:22–30

    Article  CAS  Google Scholar 

  28. Giraudeau A, Schaming D, Hao J, Farha R, Goldmann M, Ruhlmann L (2010) J Electroanal Chem 638:70–75

    Article  CAS  Google Scholar 

  29. El Kahef L, Gross M, Giraudeau A (1989) J Chem Soc Chem Commun 49:1989

    Google Scholar 

  30. Giraudeau A, Ruhlmann L, El Kahef L, Gross M (1996) J Am Chem Soc 118:2969–2979

    Article  CAS  Google Scholar 

  31. Ruhlmann L, Lobstein S, Gross M, Giraudeau A (1999) J Org Chem 64:1352–1355

    Article  CAS  Google Scholar 

  32. Giraudeau A, Lobstein S, Ruhlmann L, Melamed D, Barkigia KM, Fajer J (2001) J Porphyrins Phthalocyanines 05:793–797

    Article  CAS  Google Scholar 

  33. Ruhlmann L, Giraudeau A (1996) Chem Commun 2007

  34. Ruhlmann L, Giraudeau A (2001) Eur J Inorg Chem 659–668

  35. Schaming D, Ahmed I, Hao J, Valérie AR, Farha R, Goldmannc M, Xu HL, Giraudeaug A, Audebert P, Ruhlmann L (2011) Electrochim Acta 56:10454–10463

    Article  CAS  Google Scholar 

  36. Bruckenstein S, Shay M (1985) Electrochim Acta 30:1295–1300

    Article  CAS  Google Scholar 

  37. Kasha M (1959) Rev Mod Phys 31:162–169

    Article  CAS  Google Scholar 

  38. Sessler JL, Johnson MR, Creager SE, Fettinger JC, Ibers JA (1990) J Am Chem Soc 112:9310–9329

    Article  CAS  Google Scholar 

  39. Fajer J (2000) J Porphyrins Phthalocyanines 4:382–390

    Article  CAS  Google Scholar 

  40. Shelnutt JA, Song X, Ma J-G, Jia SL, Jentzen W, Medforth CJ (1998) Chem Soc Rev 27:31–41

    Article  CAS  Google Scholar 

  41. Barkigia KM, Berber MD, Fajer J, Medforth CJ, Renner MW, Smith KM (1990) J Am Chem Soc 112:8851–8857

    Article  CAS  Google Scholar 

  42. Sparks LD, Medforth CJ, Park MS, Chamberlain JR, Ondrias MR, Senge MO, Smith KM, Shelnutt JA (1993) J Am Chem Soc 115:581–592

    Article  CAS  Google Scholar 

  43. Anderson ME, Barrett AGM, Hoffman BM (1999) Inorg Chem 38:6143–6151

    Article  CAS  Google Scholar 

  44. Bernard C, Gisselbrecht JP, Gross M, Vogel E, Lausmann M (1994) Inorg Chem 33:2393–2401

    Article  CAS  Google Scholar 

  45. Senge MO, Renner MW, Kalisch WW, Fajer J (2000) J Chem Soc Dalton Trans 381–385

  46. D’Souza F, Zandler ME, Tagliatesta P, Ou Z, Shao J, Van CE, Kadish KM (1998) Inorg Chem 37:4567–4572

    Article  Google Scholar 

  47. Xia Y, Schaming D, Farha R, Goldmann M, Ruhlmann L (2012) New J Chem 36:588–596

    Article  CAS  Google Scholar 

  48. Schaming D, Xia Y, Thouvenot R, Ruhlmann L (2013) Chem Eur J 19:1712–1719

    Article  CAS  Google Scholar 

Download references

Acknowledgments

We thank CNRS, the University of Strasbourg (France), Université Paris-Descartes (Paris, France), Université Pierre et Marie Curie (Paris, France), Institut de Chimie des Substances Naturelles (Gif sur Yvette, France), ECE Paris Ecole d’Ingénieurs (France), and Fudan University (Shanghai, China) for funding of this work. We also thank the Université de Strasbourg for the projet “Idex Attractivité 2012” for supporting one part of this research, as well as the Oversea Study Program of Guangzhou Elite Project (GEP) for the Ph.D. grant to Zhaohui Huo. This work was also supported by Fund of senior visiting professor of Fudan University.

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Authors and Affiliations

  1. Laboratoire d’Electrochimie et de Chimie Physique du Corps Solide, Université de Strasbourg, Institut de Chimie, UMR CNRS 7177, 4 rue Blaise Pascal, CS 90032, 67081, Strasbourg cedex, France

    Zhaohui Huo & Laurent Ruhlmann

  2. Institut Parisien de Chimie Moléculaire, Sorbonne Universités, UPMC Univ Paris 6, UMR 8232, 4 Place Jussieu, 75005, Paris, France

    Iban Azcarate & Bernold Hasenknopf

  3. CNRS, Institut Parisien de Chimie Moléculaire, UMR 8232, 4 Place Jussieu, 75005, Paris, France

    Iban Azcarate & Bernold Hasenknopf

  4. Institut des NanoSciences de Paris, UMR CNRS 7588, Université Paris 6, 4 place Jussieu, boîte courrier 840, 75252, Paris, France

    Rana Farha & Michel Goldmann

  5. Laboratoire d’Analyse et Contrôle des Systèmes Complexes - LACSC-ECE Paris Ecole d’Ingénieurs, 37 Quai de Grenelle, 75015, Paris, France

    Rana Farha

  6. Université Paris Descartes, 45 rue des Saints Pères, 75006, Paris, France

    Michel Goldmann

  7. Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials and Laboratory of Advanced Materials, Fudan University, Shanghai, 200433, People’s Republic of China

    Hualong Xu

  8. ICSN CNRS, Av. de la Terrasse, 91198, Gif-sur-Yvette Cedex, France

    Emmanuel Lacôte

  9. Institut de chimie de Lyon, Université de Lyon, UMR 5265 CNRS-Université Lyon I-ESCPE Lyon, 43 Bd du 11 novembre 1918, 69616, Villeurbanne, France

    Emmanuel Lacôte

Authors
  1. Zhaohui Huo
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  2. Iban Azcarate
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  3. Rana Farha
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  4. Michel Goldmann
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  5. Hualong Xu
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  6. Bernold Hasenknopf
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  7. Emmanuel Lacôte
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  8. Laurent Ruhlmann
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Correspondence to Laurent Ruhlmann.

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Huo, Z., Azcarate, I., Farha, R. et al. Copolymeric films obtained by electropolymerization of porphyrins and dipyridyl-spacers including Dawson-type polyoxometalates. J Solid State Electrochem 19, 2611–2621 (2015). https://doi.org/10.1007/s10008-015-2828-5

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  • DOI: https://doi.org/10.1007/s10008-015-2828-5

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