Abstract
The discovery of the effect of the electrochemical promotion of catalysis (EPOC) or non-Faradaic electrochemical modification of catalytic activity (NEMCA effect) is described together with the key steps of its exploration at high pressure and high vacuum and its rationalization via electrochemical and surface science techniques. Recent attempts for its practical utilization are also surveyed.
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References
Vielstich W, Lamm A, Gasteiger H (2003) Handbook of fuel cells. Fundamentals technology and applications. Wiley, New York
Ertl G, Knötzinger H, Weitcamp J (eds) (1997) Handbook of catalysis. VCH Publishers, Weinheim
Bockris JO’M, Reddy AKM, Gamboa-Aldeco M (2000) Modern electrochemistry. Kluwer Academic/Plenum Publishers
Wieckowski A, Savinova E, Vayenas CG (eds) (2003) Catalysis and electrocatalysis at nanoparticles surfaces. Marcel Dekker, New York-Basel
Vayenas CG, Bebelis S, Pliangos C, Brosda S, Tsiplakides D (2001) Electrochemical activation of catalysis: promotion, electrochemical promotion and metal-support interactions. Kluwer/Plenum Press, New York
Wagner C (1970) Adv Catal 21:323–381
Vayenas CG, Saltsburg HM (1979) J Catal 57:296–314
Vayenas CG, Georgakis C, Michaels J, Tormo J (1981) J Catal 67:348–361
Lintz HG, Vayenas CG (1989) Angew Chem 101(6):725–732
Bockris JM, Reddy AKN (1970) Modern electrochemistry. Plenum Press, New York
Vayenas CG, Bebelis S, Ladas S (1990) Nature 343:625–627
Rath DL, Kolb DM (1981) Surf Sci 109:641–647
Vayenas CG (2000) J Electroanal Chem 486:85–90
Vayenas CG, Tsiplakides D (2000) Surf Sci 467:23–34
Frumkin A, Damaskin B (1977) J Electroanal Chem 79:259–266
Trasatti S (1990) Electrochim Acta 35:269–271
Tsiplakides D, Vayenas CG (2001) J Electrochem Soc 148(5):E189–E202
Tsiplakides D, Vayenas CG (2002) Solid State Ionics 152–153:625–639
Stoukides M, Vayenas CG (1981) J Catal 70:137–146
Stoukides M, Vayenas CG (1982) ACS Symp Series 178:181–208
Vayenas CG, Jaksic MM, Bebelis S, Neophytides SG (1996) The electrochemical activation of catalysis. In: JO’M B, Conway BE, White RE (eds) Modern aspects of electrochemistry. Kluwer Academic/Plenum Publishers, New York, pp 57–202
Bockris JO’M, Minevski ZS (1994) Electrochim Acta 39(11/12):1471–1479
Vayenas CG, Bebelis S, Neophytides S (1988) J Phys Chem 92:5083–5085
Yentekakis IV, Vayenas CG (1988) J Catal 111:170–188
Bebelis S, Vayenas CG (1989) J Catal 118:125–146
Neophytides S, Vayenas CG (1989) J Catal 118:147–163
Baltruschat H, Anastasijevic NA, Beltowska-Brzezinska M, Hambitzer G, Heitbaum J (1990) Ber Buns Phys Chem 94:996–1000
Politova TI, Sobyanin VA, Belyaev VD (1990) React Kinet Catal Lett 41(2):321–326
Mar’ina OA, Sobyanin VA (1992) Catal Lett 13:61–70
Pritchard J (1990) Nature 343:592–593
Cavalca C, Larsen G, Vayenas CG, Haller G (1993) J Phys Chem 97:6115–6119
Vayenas CG, Bebelis S, Despotopoulou S (1991) J Catal 128:415–435
Harkness I, Lambert RM (1995) J Catal 152:211–214
Mar’ina OA, Yentekakis IV, Vayenas CG, Palermo A, Lambert RM (1997) J Catal 166:218–228
Lambert R (2003) Electrochemical and chemical promotion by alkalis with metal films and nanoparticles. In: Wieckowski A, Savinova E, Vayenas CG (eds) Catalysis and electrocatalysis at nanoparticles. Marcel Dekker, Inc, New York, pp 583–611
Varkaraki E, Nicole J, Plattner E, Comninellis C, Vayenas CG (1995) J Appl Electrochem 25:978–981
Nicole J, Comninellis C (1998) J Appl Electrochem 28:223–226
Tsiplakides D, Nicole J, Vayenas CG, Comninellis C (1998) J Electrochem Soc 145(3):905–908
Marwood M, Vayenas CG (1997) J Catal 168:538–542
Nicole J, Tsiplakides D, Pliangos C, Verykios XE, Comninellis Ch, Vayenas CG (2001) J Catal 204:23–34
Verykios X (2003) Support effects on catalytic performance of nanoparticles. In: Wieckowski A, Savinova E, Vayenas CG (eds) Catalysis and electrocatalysis at nanoparticles. Marcel Dekker, Inc, New York, pp 745–783
Ladas S, Kennou S, Bebelis S, Vayenas CG (1993) J Phys Chem 97:8845–8847
Neophytides SG, Vayenas CG (1995) J Phys Chem 99:17063–17067
Pacchioni G, Illas F, Neophytides S, Vayenas CG (1996) J Phys Chem 100:16653–16661
Li X, Gaillard F, Vernoux P (2007) Top Catal 44(3):391–398
Vernoux P, Gaillard F, Karoum R, Billard A (2007) Appl Catal B Environ 731(2):73
Dorado F, de Lucas-Consuegra A, Vernoux P, Valverde JL (2007) Appl Catal B Environ 73:42
de Lucas-Consuegra A, Dorado F, Valverde JL, Karoum R, Vernoux P (2008) Catal Comm 9(1):17
Vayenas CG, Brosda S, Pliangos C (2001) J Catal 203:329–350
Brosda S, Vayenas CG (2002) J Catal 208:38–53
Brosda S, Vayenas CG, Wei J (2006) Appl Catal B Environ 68:109–124
Katsaounis A, Nikopoulou Z, Verykios XE, Vayenas CG (2004) J Catal 222(1):192–206
Katsaounis A, Nikopoulou Z, Verykios XE, Vayenas CG (2004) J Catal 226(1):197–209
Yiokari CG, Pitselis GE, Polydoros DG, Katsaounis AD, Vayenas CG (2000) J Phys Chem 104:10600–10602
Balomenou S, Tsiplakides D, Katsaounis A, Thiemann-Handler S, Cramer B, Foti G, Comninellis Ch, Vayenas CG (2004) Appl Catal B Environ 52:181–196
Tsiplakides D, Balomenou S, Katsaounis A, Archonta D, Koutsodontis C, Vayenas CG (2005) Catal Today 100:133–144
Balomenou SP, Tsiplakides D, Katsaounis A, Brosda S, Fóti G, Comninellis Ch, Thiemann-Handler S, Cramer B, Vayenas CG (2006) Solid State Ionics 177:2201–2204
Souentie S, Hammad A, Brosda S, Foti G, Vayenas CG (2008) J Appl Electrochem 38:1159–1170
Anastasijevic NA (2009) Catal Today 146:308–311
Acknowledgments
I am deeply indebted to a lot of people for the work outlined in this paper.First, to my PhD thesis advisers, H. Saltsburg and W.D. Smith, at the University of Rochester and also to Professor A. Acrivos who recommended me to MIT. Second, to my PhD students at MIT and Patras who in chronological order were J. Michaels, M. Stoukides, M. Manton, I. Yentekakis, S. Neophytides, S. Bebelis, V. Papadakis, E. Kolyfetis, D. Spartinos, P. Tsiakaras, A. Ioannides, C. Karavasilis, H. Karasali, Yi Jiang, C. Pliangos, A. Kaloyannis, M. Makri, C. Yiokari, D. Tsiplakides, Y. Bafas, C. Raptis, T. Bathas, A. Katsaounis, A. Frantzis, S. Balomenou, Y. Constantinou, A. Giannikos, D. Archonta, C. Koutsodontis, F. Sapountzi, S. Souentie, D. Presvytes, M. Tsampas, and V. Papaioannou. Third, to my MS students at MIT, B. Lee, R. Farr, J. Mulready, C. Teague-Sigal, and P. Debenedetti. Fourth, to my postdoctoral coworkers in Patras, who included many former PhD students but also Drs. P. Petrolekas, O. Mar’ina, Jiang Yi, S. Brosda, Xingang Li, and A. Hammad. Fifth, to the colleagues with whom we have collaborated in the EPOC area over the years starting from Richard Lambert, Christos Comninellis, and Nikola Anastasijevic and continuing with Milan Jaksic, Gary Haller, Carlos Cavalca, Fritz Kalhammer, Philippe Vernoux, György Fóti, Ezequiel Leiva, Gianfranco Pacchioni, Xenophon Verykios, Spyros Ladas, Ian Metcalfe, Vladimir Sobyanin, Eugene Smotkin, Ilan Riess, Leo Kriksunov, Jose Luis Valverde, and Elena Baranova. Sixth, to our brilliant and invaluable secretary Ms. Chryssa Pilisi who has contributed enormously to our effort over the years. Without her, we would have never made it that far with EPOC. Last but not least, to my parents, family, and adorable children for their patience and encouragement over the years.
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Vayenas, C.G. Bridging electrochemistry and heterogeneous catalysis. J Solid State Electrochem 15, 1425–1435 (2011). https://doi.org/10.1007/s10008-011-1336-5
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DOI: https://doi.org/10.1007/s10008-011-1336-5