Journal of Solid State Electrochemistry

, 14:169

Preparation of polyaniline–tin dioxide composites and their application in methanol electro-oxidation

Authors

  • Haili Pang
    • State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical EngineeringHunan University
  • Changting Huang
    • State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical EngineeringHunan University
    • State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical EngineeringHunan University
  • Bo Liu
    • State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical EngineeringHunan University
  • Yafei Kuang
    • State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical EngineeringHunan University
  • Xiaohua Zhang
    • State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical EngineeringHunan University
Original Paper

DOI: 10.1007/s10008-009-0892-4

Cite this article as:
Pang, H., Huang, C., Chen, J. et al. J Solid State Electrochem (2010) 14: 169. doi:10.1007/s10008-009-0892-4

Abstract

Polyaniline–tin dioxide (PANI-SnO2) composites were prepared by chemical polymerization method, and characterized by scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, and X-ray diffraction. Due to the good stability in diluted acidic solution, PANI-SnO2 composites were selected as the catalyst support and second catalyst for methanol electro-oxidation. The electrocatalytic properties of the PANI-SnO2 supported Pt catalyst (Pt/PANI-SnO2) for methanol oxidation have been investigated by cyclic voltammetry, chronoamperometry, and chronopotentiometry. Under the same loading mass of Pt, the Pt/PANI-SnO2 catalyst shows higher electrocatalytic activity towards methanol electro-oxidation than Pt/SnO2 catalyst.

Keywords

PANI-SnO2 composites Pt/PANI-SnO2 catalyst Electrocatalytic activity Methanol electro-oxidation Electrochemical properties

Copyright information

© Springer-Verlag 2009