Journal of Solid State Electrochemistry

, Volume 14, Issue 6, pp 951–956

Effect of MWCNT on the performances of the rounded shape natural graphite as anode material for lithium-ion batteries

  • Sang-Young Lee
  • Jong Hyeok Park
  • Pilkyu Park
  • Jong Hun Kim
  • Soonho Ahn
  • Kyeong-Jik Lee
  • Hyung-Dong Lee
  • Jae-Sung Park
  • Deok-Hyeong Kim
  • Yeon Uk Jeong
Original Paper

DOI: 10.1007/s10008-009-0888-0

Cite this article as:
Lee, SY., Park, J.H., Park, P. et al. J Solid State Electrochem (2010) 14: 951. doi:10.1007/s10008-009-0888-0

Abstract

Multi-walled carbon nanotube (MWCNT) with bundle-type morphology was introduced as a new functional additive working as a particle connector or an expansion absorber in the anodes of lithium-ion batteries. By controlling the dispersion process, the MWCNT bundles were successfully divided and dispersed between the host particles. The composite anode consisting of rounded shape natural graphite and 2 wt.% of MWCNT exhibited the capacity of 300 mAh g−1 at 3 C rate and excellent cyclability. The well-dispersed MWCNT bundles made it possible to relieve the large strains developed at high discharge C rates and to keep the electrical contact between the host particles during repeated intercalation/deintercalation. This study has also emphasized that when high C-rate applications of lithium-ion batteries are targeted, it is important to get optimum content of MWCNT as well as uniform dispersion of their bundles in the composite anodes.

Copyright information

© Springer-Verlag 2009

Authors and Affiliations

  • Sang-Young Lee
    • 1
  • Jong Hyeok Park
    • 2
  • Pilkyu Park
    • 3
  • Jong Hun Kim
    • 3
  • Soonho Ahn
    • 3
  • Kyeong-Jik Lee
    • 4
  • Hyung-Dong Lee
    • 4
  • Jae-Sung Park
    • 5
  • Deok-Hyeong Kim
    • 6
  • Yeon Uk Jeong
    • 6
  1. 1.Department of Chemical EngineeringKangwon National UniversityChuncheonSouth Korea
  2. 2.Department of Chemical EngineeringSungkyunkwan UniversitySuwonSouth Korea
  3. 3.Batteries Research & DevelopmentLG ChemDaejeonSouth Korea
  4. 4.SODIFF Advanced Materials Co., Ltd.YeongjuSouth Korea
  5. 5.Vitzrocell Co., Ltd./R & D CenterYesanSouth Korea
  6. 6.School of Materials Science and EngineeringKyungpook National UniversityDaeguSouth Korea

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