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Different strategies for functionalization of diamond surfaces

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Abstract

Functionalization of diamond surfaces holds considerable promise from both fundamental and applied research aspects. This review summarizes briefly the state of the art of chemical, photochemical and electrochemical strategies for the grafting of different organic functionalities on diamond. Depending on the sought-after application and the desired physical property of diamond, halogenated, aminated, carboxylated and oxidized diamond surfaces have been proposed. After a brief introduction, the review is primarily divided into two parts, presenting chemical functionalisation strategies used on oxygen-terminated diamond, followed by methods used for the formation of C–C, C–X and C–N bonds on hydrogen-terminated diamond.

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  1. Laboratoire d’Electrochimie et de Physicochimie des Matériaux et des Interfaces (LEPMI), CNRS-INPG-UJF, 1130 Rue de la Piscine, BP 75, 38402, St. Martin d’Hères Cedex, France

    Sabine Szunerits

  2. Insstitut de Recherche Interdisciplinaire (IRI), FRE CNRS 2963, Institut d’Electronique, de Microélectronique et de Nanotechnologie (IEMN), UMR CNRS-8520, Cité Scientifique, Avenue Poincaré-BP. 60069, 59652, Villeneuve d’Ascq, France

    Rabah Boukherroub

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Szunerits, S., Boukherroub, R. Different strategies for functionalization of diamond surfaces. J Solid State Electrochem 12, 1205–1218 (2008). https://doi.org/10.1007/s10008-007-0473-3

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