JBIC Journal of Biological Inorganic Chemistry

, Volume 22, Issue 2, pp 237–251

A personal perspective on the discovery of dioxygen adducts of copper and iron by Nobumasa Kitajima

Commentary

DOI: 10.1007/s00775-016-1432-1

Cite this article as:
Fujisawa, K. J Biol Inorg Chem (2017) 22: 237. doi:10.1007/s00775-016-1432-1
Part of the following topical collections:
  1. 60 Years of Oxygen Activation

Abstract

Abstract

Transition metal–dioxygen complexes have fascinated bioinorganic and inorganic chemists for over half a century. The late Nobumasa Kitajima was one of the very successful researchers in this field. Despite his short career (40 years old), he made many important contributions. This Commentary highlights his important accomplishments and how they have impacted subsequent work in this area.

Graphical Abstract

Keywords

Copper Dioxygen X-ray structure Hydrotris(pyrazolyl)borate Model complex 

Abbreviations

bppa

Bis(6-pivalamide-2-pyridylmethyl)(2-pyridylmethyl)amine

3,5-iPr2pzH

3,5-Diisopropyl-1-pyrazole

N-Et-HPTB

N, N, N’, N’-tetrakis(1-ethylbenzimidazolyl-2-methyl)-1,3-diamino-2-propanol

L0

Hydrotris(3,5-dimethyl-1-pyrazolyl)borate anion

L1

Hydrotris(3,5-diisopropyl-1-pyrazolyl)borate)borate anion

L3

Hydrotris(3-tertialy butyl-5-isoporpyl-1-pyrazolyl)borate anion

L5

Hydrotris(3,5-diphenyl-1-pyrazolyl)borate anion

L10

Hydrotris(3-adamantyl-5-isoporpyl-1-pyrazolyl)borate anion

mCPBA

m-chloroperbenzoic acid

oxyhemocyanin

Oxygenated hemocyanin

PhIO

Iodosylbenzene

Ph-bimp

2.6-Bis[bis{2-(1-methyl-4,5-diphenylimidazolyl)methyl}aminomethyl]-4-methylphenolate

TMG3tren

1,1,1-Tris{2-[N2-(1,1,3,3-tetramethylguanidino)]ethyl}amine

Tp

Hydrotris(pyrazolyl)borate

TPA

Tris{(2-pyridyl)methyl}amine

XYL–O–

α,α’-Bis{N, N-bis(2-pyridylethyl)amino}-m-xylene-2-olate

Copyright information

© SBIC 2017

Authors and Affiliations

  1. 1.Department of ChemistryIbaraki UniversityMitoJapan

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