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Study of Two Inequivalent Hydrogen Bonds in KHSO4 Single Crystals Using Nuclear Magnetic Resonance

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Abstract

Two inequivalent types of hydrogen bonds in KHSO4 were distinguished at temperatures 180–430 K using single-crystal 1H nuclear magnetic resonance (NMR) and magic-angle spinning NMR. From the 1H spin–lattice relaxation time in the laboratory frame, the hydrogen site H(1) with shorter hydrogen bonding is determined to have a longer relaxation time, while the H(2) with longer hydrogen bonds has a shorter relaxation time. The shorter T 1 indicates that the energy transfer from the nuclear spin system to the surrounding environment is more facile.

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Acknowledgments

This research was supported by the Basic Science Research program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (2015R1A1A3A04001077) and (2016R1A6A1A03012069).

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Authors and Affiliations

  1. Department of Science Education, Jeonju University, Jeonju, 560-759, Korea

    Ae Ran Lim

  2. Department of Carbon Fusion Engineering, Jeonju University, Jeonju, 560-759, Korea

    Ae Ran Lim

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  1. Ae Ran Lim
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Correspondence to Ae Ran Lim.

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Lim, A.R. Study of Two Inequivalent Hydrogen Bonds in KHSO4 Single Crystals Using Nuclear Magnetic Resonance. Appl Magn Reson 47, 1171–1177 (2016). https://doi.org/10.1007/s00723-016-0836-y

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