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1H and 19F NMR relaxation time studies in (NH4)2ZrF6 superionic conductor

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Abstract

1H and 19F spin-lattice relaxation times in polycrystalline diammonium hexafluorozirconate have been measured in the temperature range of 10–400 K to elucidate the molecular motion of both cation and anion. Interesting features such as translational diffusion at higher temperatures, molecular reorientational motion of both cation and anion groups at intermediate temperatures and quantum rotational tunneling of the ammonium group at lower temperatures have been observed. Nuclear magnetic resonance (NMR) relaxation time results correlate well with the NMR second moment and conductivity studies reported earlier.

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Authors and Affiliations

  1. Department of Physics, Bangalore University, Bangalore, India

    K. J. Mallikarjunaiah & Ramakrishna Damle

  2. Department of Physics, Indian Institute of Science, Bangalore, India

    K. P. Ramesh

  3. Department of Physics, Bangalore University, Bangalore, 560 056, India

    Ramakrishna Damle

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  1. K. J. Mallikarjunaiah
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  2. K. P. Ramesh
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  3. Ramakrishna Damle
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Correspondence to Ramakrishna Damle.

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Mallikarjunaiah, K.J., Ramesh, K.P. & Damle, R. 1H and 19F NMR relaxation time studies in (NH4)2ZrF6 superionic conductor. Appl Magn Reson 35, 449–458 (2009). https://doi.org/10.1007/s00723-009-0176-2

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  • DOI: https://doi.org/10.1007/s00723-009-0176-2

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