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Reusable and efficient polyvinylpolypyrrolidone-supported triflic acid catalyst for acylation of alcohols, phenols, amines, and thiols under solvent-free conditions

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Abstract

A triflic acid-functionalized polyvinylpolypyrrolidone was prepared and fully characterized by FT-IR, TGA, and SEM. This super acidic solid catalyst shows high catalytic activity for selective acylation of alcohols, phenols, amines, and thiols with anhydrides under solvent-free conditions at room temperature. In addition, this method features an easy to handle solid super acid catalyst and an operationally simple procedure, affording the desired acylated products in excellent yields.

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Acknowledgements

We are grateful to the University of Mazandaran for supporting our research.

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Authors and Affiliations

  1. Faculty of Chemistry, University of Mazandaran, Babolsar, Iran

    Mahgol Tajbakhsh, Mahmoud Tajbakhsh & Marzieh Heidary

  2. Department of Chemistry, Ayatollah Amoli Branch, Islamic Azad University, Amol, Iran

    Samad Khaksar

  3. School of Chemistry, College of Science, University of Tehran, Tehran, Iran

    Helia Janatian Gazvini

Authors
  1. Mahgol Tajbakhsh
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  2. Mahmoud Tajbakhsh
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  3. Samad Khaksar
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  4. Helia Janatian Gazvini
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  5. Marzieh Heidary
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Correspondence to Mahmoud Tajbakhsh.

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Tajbakhsh, M., Tajbakhsh, M., Khaksar, S. et al. Reusable and efficient polyvinylpolypyrrolidone-supported triflic acid catalyst for acylation of alcohols, phenols, amines, and thiols under solvent-free conditions. Monatsh Chem 148, 1117–1122 (2017). https://doi.org/10.1007/s00706-016-1897-1

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  • DOI: https://doi.org/10.1007/s00706-016-1897-1

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