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Complexation of the potassium cation with enniatin B: an experimental and theoretical study

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Abstract

Extraction experiments in the two-phase water-nitrobenzene system and γ-activity measurements were used to determine the stability constant of the enniatin B–K+ complex dissolved in nitrobenzene saturated with water as 105.5±0.2. Quantum mechanical calculations were applied to predict the most probable structure of this cationic complex species.

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Acknowledgments

This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Project No.: 42900/1312/3114 entitled “Environmental Aspects of Sustainable Development of Society”, and by the Czech Ministry of Education, Youth, and Sports (Project MSMT No.: 20/2015).

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Authors and Affiliations

  1. Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Czech Republic

    Emanuel Makrlík

  2. University of Chemistry and Technology, Prague, Czech Republic

    Stanislav Böhm & Petr Vaňura

Authors
  1. Emanuel Makrlík
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  2. Stanislav Böhm
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  3. Petr Vaňura
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Correspondence to Emanuel Makrlík.

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Makrlík, E., Böhm, S. & Vaňura, P. Complexation of the potassium cation with enniatin B: an experimental and theoretical study. Monatsh Chem 147, 1687–1692 (2016). https://doi.org/10.1007/s00706-016-1792-9

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  • DOI: https://doi.org/10.1007/s00706-016-1792-9

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