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Green and recyclable sulfonated graphene and graphene oxide nanosheet catalysts for the syntheses of 3,4-dihydropyrimidinones

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Abstract

Sulfated graphene and graphene oxide were used successfully as the heterogeneous catalysts for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones (-thiones) through the reaction between ethyl acetoacetate, an aldehyde, and an urea or thiourea, at room temperature in the environmentally friendly solvent. The catalysts could be separated from the reaction mixture and reused at least five times without any considerable loss of the activity. Sulfonated graphene proved to be a more efficient catalyst compared with graphene oxide.

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Acknowledgments

The authors would like to thank, Marand Branch, Islamic Azad University, Marand, Iran for the financial support of this research.

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Authors and Affiliations

  1. Department of Chemistry, Payame Noor University, Tehran, Iran

    Esmail Vessally

  2. Department of Chemistry, Marand Branch, Islamic Azad University, Marand, Iran

    Akbar Hassanpour

  3. Department of Chemistry, Tabriz Branch, Islamic Azad University, Tabriz, Iran

    Rahim Hosseinzadeh-Khanmiri, Mirzaagha Babazadeh & Jafar Abolhasani

Authors
  1. Esmail Vessally
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  2. Akbar Hassanpour
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  3. Rahim Hosseinzadeh-Khanmiri
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  4. Mirzaagha Babazadeh
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  5. Jafar Abolhasani
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Corresponding author

Correspondence to Akbar Hassanpour.

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Vessally, E., Hassanpour, A., Hosseinzadeh-Khanmiri, R. et al. Green and recyclable sulfonated graphene and graphene oxide nanosheet catalysts for the syntheses of 3,4-dihydropyrimidinones. Monatsh Chem 148, 321–326 (2017). https://doi.org/10.1007/s00706-016-1762-2

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  • DOI: https://doi.org/10.1007/s00706-016-1762-2

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