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Synthesis, characterization, and optical properties of lead(II) coordination polymers and nanosize lead oxide core of polymer

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Abstract

Two new three-dimensional lead(II) coordination polymers, [Pb2(4-bpdb)(NO3)4] n and [[Pb(4-bpdb)(NO3)(PhN2O2)]2] n , were prepared and characterized by 1H and 13C NMR, IR, and UV spectroscopy and elemental analysis. In addition, the molecular structure of [(Pb(4-bpdb)(NO3)(PhN2O2))2] n was determined by single-crystal X-ray diffraction. Photoluminescence properties of complexes showed that a good correlation exists between the structure of complexes and emission wavelengths. Utilization of cupferron ligand as a second ligand in the structure of [[Pb(4-bpdb)(NO3)(PhN2O2)]2] n enhanced the luminescence properties of it in comparison to [Pb2(4-bpdb)(NO3)4] n . Application of [[Pb(4-bpdb)(NO3)(PhN2O2)]2] n in fabrication of an organic light-emitting diode has been demonstrated. Nano-lead(II) oxide core that resulted from direct thermal decomposition of complex [[Pb(4-bpdb)(NO3)(PhN2O2)]2] n at 600 °C in air was characterized by X-ray powder diffraction and scanning electron microscopy. The photoluminescence emission spectrum of the nanosize lead(II) oxide core revealed a strong blue emission band centered at 462 nm, which might be associated with oxygen vacancies.

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Acknowledgments

Support of this work by Shahid Beheshti University and Iran University of Science and Technology is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Shahid Beheshti University, Tehran, 1983963113, Iran

    Sara Karimi Behzad, Ezzatollah Najafi, Mostafa M. Amini & Behrouz Notash

  2. Faculty of Chemistry, Iran University of Science and Technology (IUST), Tehran, 16846-13114, Iran

    Azadeh Tadjarodi & Ali Dehghani

Authors
  1. Sara Karimi Behzad
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  2. Ezzatollah Najafi
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  3. Mostafa M. Amini
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  4. Azadeh Tadjarodi
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  5. Ali Dehghani
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  6. Behrouz Notash
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Corresponding authors

Correspondence to Mostafa M. Amini or Azadeh Tadjarodi.

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Behzad, S.K., Najafi, E., Amini, M.M. et al. Synthesis, characterization, and optical properties of lead(II) coordination polymers and nanosize lead oxide core of polymer. Monatsh Chem 146, 35–45 (2015). https://doi.org/10.1007/s00706-014-1276-8

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  • DOI: https://doi.org/10.1007/s00706-014-1276-8

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