, Volume 136, Issue 9, pp 1583-1589
Date: 10 Aug 2005

CsF-Celite, an Efficient Solid State Reagent for the Syntheses of Thioesters and Thioethers

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Coupling reactions of a number of aliphatic, aromatic, and heterocyclic compounds bearing an acidic hydrogen atom attached to sulfur, with alkyl, acyl, benzyl, or benzoyl halides in acetonitrile with cesium fluoride-Celite are described. This procedure is convenient, efficient, and practical for the preparation of thioethers and thioesters.