Abstract
In this paper, we propose a simple and low-cost fabrication technique for patterning carbon nanotube (CNT) films on polydimethylsiloxane (PDMS), which can be used in flexible sensors and electronics. We demonstrate CNT patterning on both recessed and flat PDMS surfaces using a standard photolithography method. By this proposed technique, we were able to fabricate a CNT film, having a high flexibility and good conductivity, on a PDMS surface. A CNT pattern with a minimum feature resolution of 150 μm was obtained using the proposed fabrication technique. The sheet resistance of the CNT film on the PDMS surface was determined to be in the 100–280 Ω/sq range. The thickness and resultant resistivity of the CNT film can be easily controlled by controlling just the spray duration. Furthermore, the gauge factor of the proposed device is higher than that of metal and it increases as the thickness of the CNT film increases.
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References
Ahir SV, Terentjev EM (2005) Photomechanical actuation in polymer-nanotube composites. Nat Mater 4(6):491–495. doi:10.1038/nmat1391
Béfahy S, Yunus S, Burguet V, Heine JS, Dague E, Trooters M, Bertrand P (2007) Metallization process for polydimethylsiloxane (PDMS) rubber, vol 1. Cambridge Univ Press, Cambridge
Han KN, Li CA, Ngoc Bui MP, Seong GH (2010) Patterning of single-walled carbon nanotube films on flexible, transparent plastic substrates. Langmuir ACS J Surf Colloids 26(1):598–602
Jung YJ, Kar S, Talapatra S, Soldano C, Viswanathan G, Li X, Yao Z, Ou FS, Avadhanula A, Vajtai R (2006) Aligned carbon nanotube-polymer hybrid architectures for diverse flexible electronic applications. Nano Lett 6(3):413–418
Kaempgen M, Duesberg GS, Roth S (2005) Transparent carbon nanotube coatings. Appl Surf Sci 252(2):425–429. doi:10.1016/j.apsusc.2005.01.020
Koerner H, Price G, Pearce NA, Alexander M, Vaia RA (2004) Remotely actuated polymer nanocomposites—stress-recovery of carbon-nanotube-filled thermoplastic elastomers. Nat Mater 3(2):115–120. doi:10.1038/nmat1059
Lacour SP, Jones J, Suo Z, Wagner S (2004) Design and performance of thin metal film interconnects for skin-like electronic circuits. Electron Device Lett IEEE 25(4):179–181
Lacour SP, Chan D, Wagner S, Li T, Suo Z (2006a) Mechanisms of reversible stretchability of thin metal films on elastomeric substrates. Appl Phys Lett 88:204103
Lacour SP, Wagner S, Narayan RJ, Li T, Suo Z (2006b) Stiff subcircuit islands of diamondlike carbon for stretchable electronics. J Appl Phys 100:014913
Lee K, Lee SS, Lee JA, Lee K-C, Ji S (2010) Carbon nanotube film piezoresistors embedded in polymer membranes. Appl Phys Lett 96(1):013511. doi:10.1063/1.3272686
Leem DS, Kim S, Kim JW, Sohn JI, Edwards A, Huang J, Wang X, Kim JJ, Bradley DD, Demello JC (2010) Rapid patterning of single-wall carbon nanotubes by interlayer lithography. Small 6(22):2530–2534. doi:10.1002/smll.201000971
Liu C-X, Choi J-W (2009) Patterning conductive PDMS nanocomposite in an elastomer using microcontact printing. J Micromech Microeng 19(8):085019. doi:10.1088/0960-1317/19/8/085019
Patel JN, Kaminska B, Gray BL, Gates BD (2009) A sacrificial SU-8 mask for direct metallization on PDMS. J Micromech Microeng 19(11):115014. doi:10.1088/0960-1317/19/11/115014
Saran N, Parikh K, Suh DS, Munoz E, Kolla H, Manohar SK (2004) Fabrication and characterization of thin films of single-walled carbon nanotube bundles on flexible plastic substrates. J Am Chem Soc 126(14):4462–4463
Shaikh KA, Ryu KS, Goluch ED, Nam JM, Liu J, Thaxton CS, Chiesl TN, Barron AE, Lu Y, Mirkin CA (2005) A modular microfluidic architecture for integrated biochemical analysis. Proc Nat Acad Sci USA 102(28):9745
Suhr J, Koratkar N, Keblinski P, Ajayan P (2005) Viscoelasticity in carbon nanotube composites. Nat Mater 4(2):134–137. doi:10.1038/nmat1293
Unger MA, Chou HP, Thorsen T, Scherer A, Quake SR (2000) Monolithic microfabricated valves and pumps by multilayer soft lithography. Science 288(5463):113
Vilkner T, Janasek D, Manz A (2004) Micro total analysis systems. Recent developments. Anal chem 76(12):3373–3386
Wu Z, Chen Z, Du X, Logan JM, Sippel J, Nikolou M, Kamaras K, Reynolds JR, Tanner DB, Hebard AF, Rinzler AG (2004) Transparent, conductive carbon nanotube films. Science 305(5688):1273–1276. doi:10.1126/science.1101243
Acknowledgments
This work was partially supported by the Pioneer Research Center Program through the National Research Foundation of Korea funded by the Ministry of Education, Science and Technology (2010-0019453) and the National Research Foundation of Korea (NRF) grant funded by the Korea government (MEST) [2009-0076641].
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Kim, D., Yun, KS. Patterning of carbon nanotube films on PDMS using SU-8 microstructures. Microsyst Technol 19, 743–748 (2013). https://doi.org/10.1007/s00542-012-1677-8
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DOI: https://doi.org/10.1007/s00542-012-1677-8