Skip to main content
Log in

Atmospheric concentrations of polycyclic aromatic hydrocarbons (PAHs) in an urban traffic site in Erzurum, Turkey

  • Original Paper
  • Published:
Stochastic Environmental Research and Risk Assessment Aims and scope Submit manuscript

Abstract

This study presents daily and seasonal variations of PAH concentrations in Erzurum atmosphere in summer season of 2008 and in winter seasons of 2008 and 2009. Sampling location at Erzurum urban center was selected to represent the effects of traffic (University junction). 18 PAH compounds were analyzed by GC–MS. Average total PAH concentration (gas + particulate) of 18 PAH compounds were measured during 2008 winter (431 ngm−3) and summer (103 ngm−3) seasons at the University junction. Daily and seasonal variations of PAH compounds were investigated and compared with other urban centers in the literature. Multiple linear regression and artificial neural network (ANN) models were constructed to determine the impacts of meteorological parameters on measured individual PAH concentrations. Results of the multiple linear regression and ANN models indicated that wind speed, wind direction and intensity of total solar radiation were the most significant factors for the measured concentrations of PAH compounds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  • Aktan M, Bayraktar H (2010) Neural network modeling of suspended particulate matter with autoregressive structure. Ekoloji 19(74):32–37

    CAS  Google Scholar 

  • Akyüz M, Çabuk H (2010) Gas–particle partitioning and seasonal variation of polycyclic aromatic hydrocarbons in the atmosphere of Zonguldak, Turkey. Sci Total Environ 408:5550–5558

    Article  Google Scholar 

  • Allshouse WB, Pleil JD, Rappaport SM, Serre ML (2009) Mass fraction spatiotemporal geostatistics and its application to map atmospheric polycyclic aromatic hydrocarbons after 9/11. Stoch Environ Res Risk Assess 23(8):1213–1223

    Article  Google Scholar 

  • Bartolome L, Cortazar E, Raposo JC, Usobiaga A, Zuloaga O, Etxebarria N, Fernandez LA (2005) Simultaneous microwave-assisted extraction of polycyclic aromatic hydrocarbons, polychlorinated biphenyls, phthalate esters and nonylphenols in sediments. J Chromatogr A 1068:229–236

    Article  CAS  Google Scholar 

  • Caricchia AM, Chiavarini S, Pezza M (1999) Polycyclic aromatic hydrocarbons in the urban atmospheric particulate matter in the City of Naples (Italy). Atmos Environ 33:3731–3738

    Article  CAS  Google Scholar 

  • Chen JL, Wong MH, Wong YS, Tam NFY (2011) Modeling sorption and biodegradation of phenanthrene in mangrove sediment slurry. J Hazard Mater 190:409–415

    Article  CAS  Google Scholar 

  • Comrie AC (1997) Comparing neural networks and regression models for ozone forecasting. J Air Waste Manage Assoc 47:653–663

    Article  CAS  Google Scholar 

  • Daisey JM, Leyko MA, Kneip TJ (1979) Source identification and allocation of polynuclear aromatic hydrocarbon compounds in the New York City aerosol: methods and applications. In: Jones PW, Leber P (eds) polynuclear aromatic hydrocarbons. Ann Arbor, pp 201–215

  • Demircioğlu E, Sofuoğlu A, Odabaşı M (2011) Atmospheric concentrations and phase partitioning of polycyclic aromatic hydrocarbons in Izmir, Turkey. Clean-Soil Air Water 39(4):319–327

    Article  Google Scholar 

  • Dimashki M, Lim LH, Harrison RM, Harrad S (2001) Temporal trends, temperature dependence, and relative reactivity of atmospheric polycyclic aromatic hydrocarbons. Environ Sci Technol 35(11):2264–2267

    Article  CAS  Google Scholar 

  • EPA (Environmental Protection Agency) (2006) Appendix A to 40 CFR, Part 423-126. Priority pollutants. http://oaspub.epa.gov/wqsdatabase/wqsiepacriteria.repparameter

  • Esen F, Cindoruk SS, Tasdemir Y (2006) Ambient concentrations and gas/particle partitioning of polycyclic aromatic hydrocarbons in an urban site in Turkey. Environ Forensics 7:303–312

    Article  CAS  Google Scholar 

  • Esen F, Tasdemir Y, Vardar N (2008) Atmospheric concentrations of PAHs, their possible sources and gas-to-particle partitioning at a residential site of Bursa, Turkey. Atmos Res 88:243–255

    Article  CAS  Google Scholar 

  • Gaga EO, Ari A (2011) Gas–particle partitioning of polycyclic aromatic hydrocarbons (PAHs) in an urban traffic site in Eskisehir, Turkey. Atmos Res 99:207–216

    Article  CAS  Google Scholar 

  • Gaga EO, Tuncel G, Tuncel SG (2004) PAH composition of snow samples in Ankara city. Fresenius Environ Bull 13(11B):1295–1302

    CAS  Google Scholar 

  • Gcshwend PM, Hites RA (1981) Fluxes of polynuclear aromatic hydrocarbons to marine and lacustrine sediments in the northeastern United States. Geochim Cosmochim Acta 45:2359–2367

    Article  Google Scholar 

  • Georgakopoulos P, Mylona A, Athanasopoulos P, Drosinos EH, Skandamis PN (2009) Evaluation of cost-effective methods in the pesticide residue analysis of non-fatty baby foods. Food Chem 115:1164–1169

    Article  CAS  Google Scholar 

  • Harrison RM, Smith DJT, Luhana L (1996) Source apportionment of atmospheric polycyclic aromatic hydrocarbons collected from an urban location in Birmingham UK. Environ Sci Technol 30:825–832

    Article  CAS  Google Scholar 

  • Hung H, Blanchard P, Halsall CJ, Bidleman TF, Stern GA, Fellin P, Muir DCG, Barrie LA, Jantunen LM, Helm PA, Ma J, Konoplev A (2005) Temporal and spatial variabilities of atmospheric polychlorinated biphenyls (PCBs), organochlorine (OC) pesticides and polycyclic aromatic hydrocarbons (PAHs) in the Canadian Arctic: results from a decade of monitoring. Sci Total Environ 342:119–144

    Article  CAS  Google Scholar 

  • Kakimoto H, Matsumoto Y, Sakai S, Kanoh F, Arashidani K, Tang N (2002) Comparison of atmospheric polycyclic aromatic hydrocarbons and nitropolycyclic aromatic hydrocarbons in an industrialized city (Kitakyushu) and two commercial cities (Sapporo and Tokyo). J Health Sci 48:370–375

    Article  CAS  Google Scholar 

  • Kalaitzoglou M, Terzi E, Samara C (2004) Patterns and sources of particle-phase aliphatic and polycyclic aromatic hydrocarbons in urban and rural sites of western Greece. Atmos Environ 38:2545–2560

    Article  CAS  Google Scholar 

  • Kavouras IG, Euripides GS (2002) Particle size distribution of organic primary and secondary aerosol constituents in urban, background marine, and forest atmosphere. J Geophys Res-Atmos (1984–2012) 107(D8):AAC 7-1–AAC 7-12

    Google Scholar 

  • Khalili NR, Scheff PA, Holsen TM (1995) PAH source fingerprints for coke ovens, diesel and gasoline engines, highway tunnels and wood combustion emissions. Atmos Environ 29:533–542

    Article  CAS  Google Scholar 

  • Kiss G, Varga-Punchony Z, Rohrbacher G, Hlavay J (1998) Distribution of polycyclic aromatic hydrocarbons on atmospheric aerosol particles of different sizes. Atmos Res 46:253–261

    Article  CAS  Google Scholar 

  • Kulkarni P, Venkataraman C (2000) Atmospheric polycyclic aromatic hydrocarbons in Mumbai, India. Atmos Environ 34:2785–2790

    Article  CAS  Google Scholar 

  • Lee RM, Jones K (1999) Gas-particle partitioning of atmospheric PCDD/Fs: measurements and observations on modeling. Environ Sci Technol 33:3596–3604

    Article  CAS  Google Scholar 

  • Liu C, Li K, Yu L, Xu Y, Huang B, Wu J, Wang Z (2013) POPs and their ecological risk in sewage sludge of waste water treatment plants in Beijing, China. Stoch Environ Res Risk Assess 27(7):1575–1584

    Article  Google Scholar 

  • Masclet P, Bresson MA, Mouvier G (1987) Polycyclic aromatic hydrocarbons emitted by power stations, and influence of combustion conditions. Fuel 66:556–562

    Article  CAS  Google Scholar 

  • Miguel AH, Kirchstetter TW, Harley RA, Hering S (1998) Onroad emissions of particulate polycyclic aromatic hydrocarbons and black carbon from gasoline and diesel vehicles. Environ Sci Technol 32:450–455

    Article  CAS  Google Scholar 

  • Odabaşı M, Vardar N, Sofuoğlu A, Tasdemir Y, Holsen TM (1999) Polycyclic aromatic hydrocarbons PAHs in Chicago air. Sci Total Environ 227:57–67

    Article  Google Scholar 

  • Odabaşı M, Çetin E, Sofuoğlu A (2006) Determination of octanol–air partition coefficients and supercooled liquid vapor pressures of PAHs as a function of temperature: application to gas–particle partitioning in an urban atmosphere. Atmos Environ 40:6615–6625

    Article  Google Scholar 

  • Papageorgopoulou A, Manoli E, Touloumi E, Samara C (1999) Polycyclic aromatic hydrocarbons in the ambient air of Greek towns in relation to other atmospheric pollutants. Chemosphere 39(13):2183–2199

    Article  CAS  Google Scholar 

  • Rey-Salgueiro L, Pontevedra-Pombal X, Álvarez-Casas M, Martínez-Carballo E, García-Falcón MS, Simal-Gándara J (2009) Comparative performance of extraction strategies for polycyclic aromatic hydrocarbons in peats. J Chromatogr A 1216:5235–5241

    Article  CAS  Google Scholar 

  • Rogge WF, Hildemann LM, Mazurek MA, Cass GR (1993) Sources of fine organic aerosol, 3. Road dust, tire debris, and organometallic brake lining dust: roads as sources and sinks. Environ Sci Technol 27:1892–1904

    Article  CAS  Google Scholar 

  • Sienra MR, Rosazza NG, Préndez M (2005) Polycyclic aromatic hydrocarbons and their molecular diagnostic ratios in urban atmospheric respirable particulate matter. Atmos Res 75:267–281

    Article  CAS  Google Scholar 

  • Simcik MF, Franz TP, Zhang H, Eisenreich SJ (1997) Gas-particle partitioning of PCBs and PAHs in the Chicago urban and adjacent coastal atmosphere: states of equilibrium. Environ Sci Technol 31:2141–2147

    Article  CAS  Google Scholar 

  • Simcik MF, Eisenreich SJ, Lioy PJ (1999) Source apportionment and source/sink relationships of PAHs in the coastal atmosphere of Chicago and Lake Michigan. Atmos Environ 33:5071–5079

    Article  CAS  Google Scholar 

  • Sitaras IE, Bakeas EB, Siskos PA (2004) Gasyparticle partitioning of seven volatile polycyclic aromatic hydrocarbons in a heavy traffic urban area. Sci Total Environ 327:249–264

    Article  CAS  Google Scholar 

  • Taşdemir Y, Esen F (2007) Urban air PAHs: concentrations, temporal changes and gas/particle partitioning at a traffic site in Turkey. Atmos Res 84:1–12

    Article  Google Scholar 

  • Vardar N, Esen F, Tasdemir Y (2008) Seasonal concentrations and partitioning of PAHs in a suburban site of Bursa, Turkey. Environ Pollut 155:298–307

    Article  CAS  Google Scholar 

  • Wane CH, Kim AW, Beriro DJ, Cave MR, Knights K, Moss-Hayes V, Nathanail PC (2014) Polycyclic aromatic hydrocarbons (PAH) and polychlorinated biphenyls (PCB) in urban soils of Greater London, UK. Appl Geochem 51:303–314

    Article  Google Scholar 

  • Wang XY, Li QB, Luo YM, Ding Q, Xi LM, Ma JM, Li Y, Liu YP, Cheng CL (2010) Characteristics and sources of atmospheric polycyclic aromatic hydrocarbons (PAHs) in Shanghai, China. Environ Monit Assess 165:295–305

    Article  CAS  Google Scholar 

  • Yunker MB, Macdonald RW, Vingarzan R, Mitchell RH, Goyette D, Sylvestre S (2002) PAHs in the Fraser River Basin: a critical appraisal of PAH ratios as indicators of PAH source and composition. Org Geochem 33:489–515

    Article  CAS  Google Scholar 

  • Zhang S, Zhang W, Wang K, Shen Y, Hu L, Wang X (2009) Concentration, distribution and source apportionment of atmospheric polycyclic aromatic hydrocarbons in the southeast suburb of Beijing, China. Environ Monit Assess 151:197–207

    Article  CAS  Google Scholar 

  • Zhao B, Zhang S, Zhou Y, He D, Li Y, Ren M, Xu Z, Fang J (2015) Characterization and quantification of PAH atmospheric pollution from a large petrochemical complex in Guangzhou: GC–MS/MS analysis. Microchem J 119:140–144

    Article  CAS  Google Scholar 

Download references

Acknowledgments

We would like to thank for the financial support provided by TUBITAK Grant No. 107Y021.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Hanefi Bayraktar.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Paloluoğlu, C., Bayraktar, H., Aktan, M. et al. Atmospheric concentrations of polycyclic aromatic hydrocarbons (PAHs) in an urban traffic site in Erzurum, Turkey. Stoch Environ Res Risk Assess 30, 1223–1234 (2016). https://doi.org/10.1007/s00477-015-1110-9

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00477-015-1110-9

Keywords

Navigation