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Fine structure of As

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Zeitschrift für Physik D Atoms, Molecules and Clusters

Abstract

The energies of the As fine structure components 4p4 3 P 1 and 4p4 3 P 0 have been determined relative to the 4p4 3P2 ground state by using photodetachment electron spectroscopy. Fine structure splittings of ΔE(3 P 13 P 2) = 125(3) meV and ΔE(3 P 03 P 2) = 166(5) meV have been obtained. It is the first experimental determination of the energy of the J = 1 level and an improvement of the accuracy for the J = 0 level. Previous isoelectronic extrapolations are consistent with the experimental values.

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References

  1. Buckman, S.J., Clark, C.W.: Rev. Mod. Phys. 66, 539 (1994)

    Article  ADS  Google Scholar 

  2. Blondel, C.: Phys. Scr. T 58, 31 (1995)

    Article  ADS  Google Scholar 

  3. Hotop, H., Lineberger, W.C.: J. Phys. Chem. Ref. Data 14, 731 (1985)

    Article  ADS  Google Scholar 

  4. Salomonson, S., Warston, H., Lindgren, I.: Phys. Rev. Lett. 76, 3092 (1996)

    Article  ADS  Google Scholar 

  5. Froese Fischer, C., Brage, T.: Can. J. Phys. 70, 1283 (1992)

    Article  ADS  Google Scholar 

  6. Feldmann, D., Rackwitz, R., Heinicke, E., Kaiser, H.J.: Z. Phys. A 282, 143 (1977)

    Article  ADS  Google Scholar 

  7. Haeffler, G., Hanstorp, D., Kiyan, I., Klinkmüller, A.E., Ljungblad, U., Pegg, D.J.: Phys. Rev. A 53, 4127 (1996)

    Article  ADS  Google Scholar 

  8. Kristensen, P., Stapelfeldt, H., Balling, P., Andersen, T., Haugen, H.K.: Phys. Rev. Lett. 71, 3435 (1993)

    Article  ADS  Google Scholar 

  9. Thøgersen, J., Steele, L.D., Scheer, M., Haugen, H.K., Kristensen, P., Balling, P., Stapelfeldt, H., Andersen, T.: Phys. Rev. A 53, 3023 (1996)

    Article  ADS  Google Scholar 

  10. Thøgersen, J., Steele, L.D., Scheer, M., Brodie, C.A., Haugen, H.K.: J. Phys. B 29, 1323 (1996)

    Article  ADS  Google Scholar 

  11. Neumark, D.M., Lykke, K.R., Andersen, T., Lineberger, W.C.: Phys. Rev. A 32, 1890 (1985)

    Article  ADS  Google Scholar 

  12. Kristensen, P., Petrunin, V.V., Andersen, H.H., Andersen, T.: Phys. Rev. A 52, R2508 (1995)

    Article  ADS  Google Scholar 

  13. Breyer, F., Frey, P., Hotop, H.: Z. Phys. A 286, 133 (1978)

    Article  ADS  Google Scholar 

  14. Feigerle, C.S., Corderman, R.R., Lineberger, W.C.: J. Chem. Phys. 74, 1513 (1981)

    Article  ADS  Google Scholar 

  15. Blondel, C., Crance, M., Delsart, C., Giraud, A.: J. Phys. B 24, 3575 (1991)

    Article  ADS  Google Scholar 

  16. Stapelfeldt, H., Balling, P., Brink, C., Haugen, H.K.: Phys. Rev. Lett. 67, 1731 (1991)

    Article  ADS  Google Scholar 

  17. Zollweg, R.J.: J. Chem. Phys. 50, 4251 (1969)

    Article  ADS  Google Scholar 

  18. Hotop, H., Lineberger, W.C.: J. Phys. Chem. Ref. Data 4, 539 (1975)

    Article  ADS  Google Scholar 

  19. Cohen, E.R., Taylor, B.N.: J. Phys. Chem. Ref. Data 17, 1795 (1988)

    Article  ADS  Google Scholar 

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Haeffler, G., Ljungblad, U., Kiyan, I.Y. et al. Fine structure of As . Z Phys D - Atoms, Molecules and Clusters 42, 263–266 (1997). https://doi.org/10.1007/s004600050365

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  • DOI: https://doi.org/10.1007/s004600050365

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