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Intersector element partitioning in tourmaline: a potentially powerful single crystal thermometer

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Abstract

Hourglass sector zoning, and related polar overgrowths, are common features of metamorphic tourmaline, developing as a result of variations in element preference on the different growth surfaces. For sector-zoned crystals, three domains are present for each growth zone (c +, c - and a), with compositional differences most distinct for Ca and Ti, and among c + and c - sectors. Intersector differences vary, commonly showing decreasing fractionation from core to rim attributed to increasing metamorphic grade. Here we show that intersector element partitioning is temperature dependent and derive empirical geothermometers based on c +-c -and c +-a partitioning of Ca and Ti. These thermometers are applicable over a range of temperatures and bulk-rock compositions. Intersector partitioning is not affected by re-equilibration and records and preserves complete T-histories of individual tourmaline grains from prograde to peak and on to retrograde growth. Information on element mobility is preserved by tourmaline composition, because intersector partitioning is independent of element concentration. These factors make intersector partitioning an ideal tool to elucidate the thermal history of tourmaline grains and thus their host environment and tourmaline's refractory nature preserves these signatures even into the sedimentary record.

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References

  • Bebout GE, Nakamura E (2003) Record in metamorphic tourmalines of subduction-zone devolatilization and boron cycling. Geology 31:407-410

    Article  Google Scholar 

  • Blencoe JG, Guidotti CV, Sassi FP (1994) The paragonite-muscovite solvus: II numerical geothermometers for natural quasibinary paragonite-muscovite pairs, Geochim Cosmochim Acta 58:2277-2288

    Article  Google Scholar 

  • Bohlen SR, Wall VJ, Boettcher AL (1983) Experimental investigations and geological applications of equilibria in the system FeO-TiO2-Al2O3-SiO2-H2O. Am Mineral 68:1049-1058

    Google Scholar 

  • Carlson WD (2002) Presidential address; scales of equilibrium and rates of equilibration during metamorphism. Am Mineral 87:185-204

    Article  Google Scholar 

  • Elkins LT, Grove TL (1990) Ternary feldspar experiments and thermodynamic models. Am Mineral 75:544-559

    Google Scholar 

  • Faure G (1986) Principles of isotope geology, 2nd edn. Wiley, London, 589pp

  • von Goerne G, Franz G, Wirth R (1999a) Hydrothermal synthesis of large dravite crystals by the chamber method. Eur J Mineral 11:1061-1078

    Article  Google Scholar 

  • von Goerne G, Franz G, Robert JL (1999b) Upper thermal stability of tourmaline + quartz in the system MgO-Al2O3-SiO2-B2O3-H2O and Na2O-MgO-Al2O3-SiO2-B2O3-H2O-HCl in hydrothermal solutions and siliceous melts. Can Mineral 37:1025-1039

    Google Scholar 

  • Grew ES, Anovitz LM (1996) Boron: mineralogy, petrology, and geochemistry, Rev Mineral 33, Mineralogical Society of America, Washington, 864pp

  • Grover JE, Orville PM (1969) The partitioning of cations between coexisting single- and multi-site phases with application to the assemblages: orthopyroxene-clinopyroxene and orthopyroxene-olivine. Geochim Cosmochim Acta 33:205-226

    Article  Google Scholar 

  • Henry DJ, Dutrow BL (1990) Ca substitution in Li-poor aluminous tourmaline. Can Mineral 28:111-124

    Google Scholar 

  • Henry DJ, Dutrow BL (1992) Tourmaline in a low-grade clastic metasedimentary rock: an example of the petrogenetic potential of tourmaline. Contrib Mineral Petrol 112:203-218

    Article  Google Scholar 

  • Henry DJ, Dutrow BL (1996) Metamorphic tourmaline and its petrologic applications. In: Grew ES, Anovitz LM (eds) Boron: mineralogy, petrology, and geochemistry. Rev Mineral 33:503-557

  • Henry DJ, Dutrow BL (2001) Compositional zoning and element partitioning in nickeloan tourmaline from a metamorphosed karstbauxite from Samos, Greece. Am Mineral 80:1130-1142

    Article  Google Scholar 

  • Henry DJ, Kirkland BL, Kirkland DW (1999) Sector-zoned tourmaline from the cap rock of a salt dome. Eur J Mineral 11:263-280

    Article  Google Scholar 

  • Henry DJ, Guidotti CV, Thomson JA (2005) The Ti-saturation surface for low-to-medium pressure metapelitic biotite: implications for geothermometry and Ti-substitution mechanisms. Am Mineral 90:316-328

    Article  Google Scholar 

  • van Hinsberg VJ, Schumacher JC, Kearns S (2004) A new type of sector zoning in tourmaline: Inferences and applications. Geol Soc Am Abstr Prog 36:225

    Google Scholar 

  • van Hinsberg VJ, Schumacher JC, Kearns S, Mason PRD, Franz G (2006) Hourglass sector zoning in metamorphic tourmaline and resultant major and trace element fractionation. Am Mineral 91:717-728

    Article  Google Scholar 

  • van Hinsberg VJ, Zinngrebe E, de Wijs CJ, Vriend SP (2007) Thermo-chronology of the Barlet metamorphic basement unit: evidence for a Stephanian thermal event linked to Sb mineralizations in the Haut Allier, France, (in press)

  • Holdaway MJ (2000) Application of new experimental and garnet Margules data to the garnet-biotite geothermometer. Am Mineral 85:881-892

    Article  Google Scholar 

  • Holdaway MJ (2001) Recalibration of the GASP geobarometer in light of recent garnet and plagioclase activity models and versions of the garnet-biotite geothermometer. Am Mineral 86:1117-1129

    Article  Google Scholar 

  • Kotzer TG, Kyser TK, King RW, Kerrich R (1993) An empirical oxygen- and hydrogenisotope geothermometer for quartz-tourmaline and tourmaline-water. Geochim Cosmochim Acta 57:3421-3426

    Article  Google Scholar 

  • Pownceby MI, Wall VI, O’Neill HS (1991) An experimental study of the effect of Ca upon garnet-ilmenite Fe-Mn exchange equilibria, Am Mineral 76:1580-1588

    Google Scholar 

  • Pyle JM, Spear FS (2000) An empirical garnet (YAG)—xenotime thermometer, Contrib Mineral Petrol 138:51-58

    Article  Google Scholar 

  • Pyle JM, Spear FS, Rudnick RF, McDonough WF (2001) Monazite-xenotime-garnet equilibrium in metapelites and a new monazite-garnet thermometer, J Petrol 42:2083-2107

    Article  Google Scholar 

  • Spear FS (1993) Metamorphic phase equilibria and pressure-temperature-time paths. Miner Soc Am Monogr 1:799

    Google Scholar 

  • Sperlich R (1990) Zoning and crystal chemistry of tourmalines in prograde metamorphic sequences of the Central Alps. PhD thesis, University of Basel, Switzerland, 51pp

  • Sperlich R, Giere R, Frey M (1996) Evolution of compositional polarity and zoning in tourmaline during prograde metamorphism of sedimentary rocks in the Swiss Central Alps. Am Mineral 81:1222-1236

    Article  Google Scholar 

  • Voll G (1969) Klastische Mineralien aus den Sedimentserien der Schottischen Highlands und ihr Schiksal bei aufsteigender Regional- und Kontaktmetamorphose. Habilitations These, Technische Universität Berlin

    Google Scholar 

  • Zack T, Moraes R, Kronz A (2004) Temperature dependence of Zr in rutile: Empirical calibration of a rutile thermometer. Contrib Mineral Petrol 148:471-488

    Article  Google Scholar 

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Acknowledgments

We thank Stuart Kearns for advice and help with all aspects of microbeam analyses, and for countless discussions. Simon Vriend is thanked for arranging access to the Utrecht University EMP facilities in 2002. VvH acknowledges financial support from the University of Bristol through a strategic postgraduate scholarship. Part of this research was funded through a NERC small research grant.

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  1. Department of Earth Sciences, University of Bristol, Wills Memorial Building, Queen's Road, Bristol, BS8 1RJ, UK

    Vincent J. van Hinsberg & John C. Schumacher

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  1. Vincent J. van Hinsberg
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  2. John C. Schumacher
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Correspondence to Vincent J. van Hinsberg.

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Communicated by J. Hoefs.

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van Hinsberg, V.J., Schumacher, J.C. Intersector element partitioning in tourmaline: a potentially powerful single crystal thermometer. Contrib Mineral Petrol 153, 289–301 (2007). https://doi.org/10.1007/s00410-006-0147-7

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  • DOI: https://doi.org/10.1007/s00410-006-0147-7

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