Original contribution

Rheologica Acta

, Volume 45, Issue 4, pp 435-443

First online:

Self-assembled nanoribbons and nanotubes in water: energetic vs entropic networks

  • Pierre TerechAffiliated withUMR 5819 (CEA-CNRS-Université Joseph Fourier), CEA-Grenoble, DRFMC Email author 
  • , Séverine FriolAffiliated withUMR 5819 (CEA-CNRS-Université Joseph Fourier), CEA-Grenoble, DRFMC
  • , Neralagatta SangeethaAffiliated withDepartment of Organic Chemistry, Indian Institute of Science
  • , Yeshayahu TalmonAffiliated withDepartment of Chemical Engineering, Technion-Israel Institute of Technology
  • , Uday MaitraAffiliated withDepartment of Organic Chemistry, Indian Institute of Science

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We present a comparative investigation of two opposite classes of self-assembled fibrillar networks. Ribbons and tubes having cross-sectional dimensions in the nanoscale can be formed in aqueous solutions of steroids derived, respectively, from deoxycholic (DC) and lithocholic (LC) acids. Rheological features distinguish energetic networks of DC ribbons rigidly fixed in cylindrical bundles and entropic transient networks of LC tubes weakly interacting in shear-sensitive suspensions. The two classes are characterized by their frequency sweep profiles, viscoelastic linear domains, scaling laws of the elastic shear modulus vs concentration, kinetics of formation of the networks, and their optical birefringence aspects. A theoretical context for networks of rigid fibers is used to account for the scaling exponents α in the G’ (and σ*) ∝C α laws (α=2.0 and 1.0, respectively, for DC and LC). The evolution observed in DC gels from ribbons to cylindrical fibers with monodisperse sections made up with four ribbons is an indication of an equilibrated balance between face-to-face attractions and untwisting elastic processes of the constitutive ribbons.


Self-assembling Networks Fibers Tubes Ribbons Rheology