Abstract
Highly uniform polymer latex particles with controlled particle size have been widely applied in many fields such as nanotechnology, drug delivery, biomedical separation, and material templates. Since the particle size plays a critical role in determining the application fields, various technologies such as two-stage swelling method and dynamic swelling method have been used to control the particle size in the polymerization process. However, these methods usually need a multi-step polymerization reaction and long reaction time. This review focuses on a method of controlling particle size, that is, particle coagulation technology. Particle coagulation technology can be used to produce large sized, monodispersed polymer particles by soap-free emulsion polymerization, macroemulsion polymerization, and dispersion polymerization. In this review article, an overview of the concept of particle coagulation is given, followed by the description of the particle coagulation process in different polymerization systems. Some representative publications about particle coagulation were also reviewed, especially the effect of reaction parameters on the particle coagulation extent and time. Finally, the relationship between the particle coagulation and particle size distribution is reviewed extensively.
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Huang T, Huang X, Sun X, Zhou Y, Bai Y, Yan D (2014) Chem Commun 50:7363–7366
Rao J, Geckeler K (2011) Prog Polym Sci 36:887–913
Huang H, Ding Y, Chen X, Chen Z, Kong XZ (2016) Chem Eng J 289:135–141
Song JS, Tronc F, Winnik MA (2004) J Am Chem Soc 126:6562–6563
Ugelstad J, Kaggerud KH, Hansen FK, Berge A (1979) Macromol Chem Phys 180:737–744
Okubo M, Shiozaki M, Tsujihiro M, Tsukuda Y (1991) Colloid Polym Sci 269:222–226
Okubo M, Wang Z, Yamashita T, Ise E, Minami H (2001) J Polym Sci Part A: Polym Chem 39:3106–3111
Kim DJ, Kim KS (2002) AICHE J 48:2499–2509
Kim DJ, Kim KS, Zhao QQ (2003) J Nanopart Res 5:211–223
Friedlander SK, Wang CS (1966) J Colloid Inter Sci 22:126–132
Xu S, Sun Z (2011) Soft Matter 7:11298–11308
Cho KD, Jang K, Yang GH, Chang JG, Ha KR, Park JW, Song SM (2002) J Appl Polym Sci 84:276–282
Liu B, Sun S, Zhang M, Ren L, Zhang H (2015a) Colloids Surf A Physicochem Eng Asp 484:81–88
Liu B, Wang Y, Zhang M, Zhang H (2016a) Polymers 8:55
Feeney PJ, Napper DH, Gilbert RG (1987) Macromolecules 20:2922–2930
Chern CS, Lin SY, Chen LJ, Wu SC (1997) Polymer 38:1977–1984
Chern CS (2006) Prog Polym Sci 31:443–486
Ishii H, Kuwasaki N, Nagao D, Konno M (2015) Polymer 77:64–69
Choi YS, Choi MH, Wang KH, Kim SO, Kim YK, Chung IJ (2001) Macromolecules 34:8978–8985
Zhao Y, Chen Z, Zhu X, Möller M (2016) Macromolecules 49:1552–1562
Feeney PJ, Napper DH, Gilbert RG (1984) Macromolecules 17:2520–2529
Peach S (1998) Macromolecules 31:3372–3373
Dobrowolska ME, van Esch JH, Koper GJ (2013) Langmuir 29:11724–11729
Dobrowolska ME, Ger JM (2014) Soft Matter 10:1151–1154
Yamamoto T, Nakayama M, Kanda Y, Higashitani K (2006) J Colloid Inter Sci 297:112–121
Yamamoto T (2012) Colloid Polym Sci 290:1023–1031
Yamamoto T, Kawaguchi K (2015) Colloid Polym Sci 293:1003–1006
Yamamoto T, Kawaguchi K, Takahashi Y (2016) Colloids Surf A Physicochem Eng Asp 502:1–5
Ito F, Makino K, Ohshima H, Terada H, Omi S (2004) Colloids Surf A Physicochem Eng Asp 233:171–179
Gu S, Mogi T, Konno M (1998) J Colloid Inter Sci 207:113–118
Shibuya K, Nagao D, Ishii H, Konno M (2014) Polymer 55:535–539
Ishii H, Ishii M, Nagao D, Konno M (2014) Polymer 55:2772–2779
Gu S, Akama H, Nagao D, Kobayashi Y, Konno M (2004) Langmuir 20:7948–7951
Lee J, Ha JU, Choe S, Lee CS, Shim SE (2006) J Colloid Inter Sci 298:663–671
Konno M, Nagao D (2014) Monodisperse polymer particles. Encyclopedia of polymer science and technology. Wiley Interscience, New York
Li Z, Cheng H, Han CC (2012) Macromolecules 45:3231–3239
Nagao D, Yamada Y, Inukai S, Ishii H, Konno M, Gu S (2015) Polymer 68:176–182
Chern CS, Lin FY (1996) J Appl Polym Sci 61:989–1001
Mayer MJJ, Meuldijk J, Thoenes D (1996) J Appl Polym Sci 59:83–90
Sajjadi S (2000) J Polym Sci Part A: Polym Chem 38:3612–3630
Feiz S, Navarchian AH (2012) Chem Eng Sci 69:431–439
Ohshima H (2013) Colloid Polym Sci 291:3013–3016
Liu B, Zhang M, Zhou C, Ren L, Cheng H, Ao Y, Zhang H (2013) Colloid Polym Sci 291:2385–2398
Smith WV, Ewart RH (1948) J Chem Phys 16:592–599
Gardon JL (1968a) J Polym Sci Part A: Polym Chem 6:623–641
Gardon JL (1968b) J Polym Sci Part A: Polym Chem 6:643–664
Liu B, Zhang M, Cheng H, Fu Z, Zhou T, Chi H, Zhang H (2014a) Colloid Polym Sci 292:519–525
Liu B, Zhang M, Gui Y, Chen D, Zhang H (2014b) Colloids Surf A Physicochem Eng Asp 452:159–164
Kim G, Lim S, Lee BH, Shim SE, Choe S (2010) Polymer 51:1197–1205
Paine AJ (1990) Macromolecules 23:3109–3117
Liu B, Zhang M, Wu G, Zhang H (2016b) Colloids Surf A Physicochem Eng Asp 500:127–136
Liu B, Meng W, Zhang M, Zhang HX (2016c) RSC Adv 6:88701–88706
Liu B, Meng W, Wang P, Zhang M, Zhang H (2016d) Eur Polym J 83:278–287
Richez AP, Yow HN, Biggs S, Cayre OJ (2013) Prog Polym Sci 38:897–931
Sun JT, Hong CY, Pan CY (2013) Polym Chem 4:873–881
Smeets NM, Hutchinson RA, McKenna TF (2011) ACS Macro Lett 1:171–174
Chou IC, Chiu WY (2013) Macromolecules 46:3561–3569
Zhang F, Cao L, Yang W (2010a) Macromol Chem Phys 211:744–751
Zhang F, Ma Y, Liu L, Yang W (2010b) J Phys Chem B 114:10970–10978
Cho YS, Shin CH, Han S (2016) Nanoscale Res Lett 11:1–9
Sonawane SL, Asha SK (2013) ACS Appl Mater Interfaces 5:12205–12214
Bouvier-Fontes L, Pirri R, Asua JM, Leiza JR (2005) Macromolecules 38:1164–1171
Song JS, Winnik MA (2005) Macromolecules 38:8300–8307
Peng B, Imhof A (2015) Soft Matter 11:3589–3598
Minami H, Mizuta Y, Suzuki T (2013) Langmuir 29:554–560
Xia L, Zhang M, Yuan C, Rong M (2011) J Mater Chem 21:9020–9026
Deng Z, Zhu H, Peng B, Chen H, Sun Y, Gang X, Jin P, Wang J (2012) ACS Appl Mater Interfaces 4:5625–5632
Kim JW, Cho J, Cho J, Park BJ, Kim YJ, Choi KH, Kim JW (2016) Angew Chem In Ed 55:4509–4513
Liu Y, Ma Y, Liu L, Yang W (2015b) J Colloid Inter Sci 445:268–276
Chen H, Shen H, Wu H, Wang M, Lee C, Chiu W, Chen W (2015) J Mater Chem C 3:3318–3328
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The authors appreciate the financial support from the National Natural Scientific Foundation of China (No. 51573022).
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Liu, B., Fu, Z., Han, Y. et al. Facile synthesis of large sized and monodispersed polymer particles using particle coagulation mechanism: an overview. Colloid Polym Sci 295, 749–757 (2017). https://doi.org/10.1007/s00396-017-4058-0
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DOI: https://doi.org/10.1007/s00396-017-4058-0