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Conductometric and fluorescence probe investigations of molecular interactions between dodecyltrimethylammonium bromide and dipeptides

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Abstract

The effect of five dipeptides (glycylglycine, glycyl-l-valine, glycyl-l-leucine, glycyl-l-glutamine, and l-alanyl-l-glutamine) on the micellar properties of catonic surfactant dodecyltrimethylammonium bromide (DTAB) has been investigated by electrical conductivity and fluorescence spectroscopy. From the conductivity data, the critical micellar concentration (c cmc), counterion binding constant (β), and thermodynamic parameters of micellization (ΔG o m , ΔH o m and ΔS o m ) have been calculated. The effect of dipeptides on the micellar properties of DTAB depends upon their nature and concentration as well as on temperature and has been used to study the interactions present in the micellar systems. Enthalpy–entropy compensation effect has also been observed. The pyrene fluorescence spectra were used as an index for the estimation of micropolarity of micellar produced by the interaction of DTAB with dipeptides and the aggregation behavior of DTAB. Comparison on the interactions between different types of surfactants and dipeptide showed that the order of the strength for these interactions is TX-100 < DTAB < SAS < SDS.

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Acknowledgments

The project is financially supported by the Natural Science Foundation of China (No. 20973158, J1210060) and Training Programs of Innovation and Entrepreneurship for Undergraduates of Zhengzhou University (2013).

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Authors and Affiliations

  1. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, Henan, 450001, People’s Republic of China

    Shuangyan Wu, Zhenning Yan, Xiangli Wen, Cuiying Xu & Qi Pan

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  1. Shuangyan Wu
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  2. Zhenning Yan
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  3. Xiangli Wen
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Correspondence to Zhenning Yan.

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Wu, S., Yan, Z., Wen, X. et al. Conductometric and fluorescence probe investigations of molecular interactions between dodecyltrimethylammonium bromide and dipeptides. Colloid Polym Sci 292, 2775–2783 (2014). https://doi.org/10.1007/s00396-014-3322-9

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  • DOI: https://doi.org/10.1007/s00396-014-3322-9

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