Skip to main content
SpringerLink
Log in

Preparation of hollow poly(divinyl benzene) particles with multiple holes in the shell by microsuspension polymerization with the SaPSeP method

  • Short Communication
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

Hollow polymer particles with multiple holes in the shell were prepared by aqueous microsuspension polymerization of micrometer-sized, monodisperse divinylbenzene/n-hexadecane droplets in the presence of sodium dodecyl sulfate (SDS) at concentrations above 4 mM utilizing the Self-assembling Phase-Separated Polymer (SaPSeP) method developed by the authors. The total surface area of the holes per particle increased with an increase in the SDS concentration. At [SDS] = 10 mM, “flower-like” non-spherical particles were formed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

References

  1. Okubo M, Ichikawa K, Fujimura M (1991) Colloid Polym. Sci. 269:1257

    Article  CAS  Google Scholar 

  2. Okubo M, Ichikawa K (1994) Colloid Polym. Sci. 272:933

    Article  CAS  Google Scholar 

  3. Tiarks F, Landfester K, Antonietti M (2001) Langmuir 17:908

    Article  CAS  Google Scholar 

  4. Schuler C, Caruso F (2001) Biomacromolecules 2:921

    Article  CAS  Google Scholar 

  5. Jang J, Ha H (2002) Langmuir 18:5613

    Article  CAS  Google Scholar 

  6. McDonald C, Devon MJ (2002) Adv. Colloid Interface Sci. 99:181

    Article  CAS  Google Scholar 

  7. Ali MM, Stöver HD (2003) Macromolecules 36:1793

    Article  CAS  Google Scholar 

  8. Okubo M, Okabe M, Shiba K (2003) Macromol. Symp. 195:115

    Article  CAS  Google Scholar 

  9. Zhang YW, Jiang M, Zhao JX, Wang ZX, Dou HJ, Chen DY (2005) Langmuir 21:1531

    Article  CAS  Google Scholar 

  10. Okubo M, Minami H, Yamashita T (1996) Macromol. Symp. 101:509

    CAS  Google Scholar 

  11. Okubo M, Minami H (1997) Colloid. Polym. Sci. 275:992

    Article  CAS  Google Scholar 

  12. Okubo M, Shiozaki M, Tsujihiro M, Tsukuda Y (1991) Colloid. Polym. Sci. 269:222

    Article  CAS  Google Scholar 

  13. Okubo M, Shiozaki M (1993) Polymn. In. 30:469

    Article  CAS  Google Scholar 

  14. Okubo M, Ise E, Yamashita T (1999) J. Appl. Polym. Sci. 74:278

    Article  CAS  Google Scholar 

  15. Okubo M, Konishi Y, Minami H (2000) Colloid. Polym. Sci. 278:659

    Article  CAS  Google Scholar 

  16. Okubo M, Minami H, Oshima Y (2005) Polymer 46:1051

    Article  Google Scholar 

  17. Konishi Y, Okubo M, Minami H (2003) Colloid Polym. Sci. 281:123

    Article  CAS  Google Scholar 

  18. Okubo M, Konishi Y, Minami H (2001) Colloid. Polym. Sci. 279:519

    Article  CAS  Google Scholar 

  19. Okubo M, Konishi Y, Minami H (2003) Progr. Colloid. Polym. Sci. 124:54

    Google Scholar 

  20. Minami H, Kobayashi H, Okubo M (2005) Langmuir 21:5655

    Article  CAS  Google Scholar 

  21. Tuncel A, Tuncel M, Salih B (1999) J. Appl. Polym. Sci. 71:2271

    Article  CAS  Google Scholar 

  22. Tuncel A (1999) J. Appl. Polym. Sci. 71:2291

    Article  CAS  Google Scholar 

  23. Ma GH, Su ZG, Omi S, Sundberg D, Stubbs J (2003) J. Colloid Interface Sci. 266:282

    Article  CAS  Google Scholar 

  24. Guan G, Zhang Z, Wang Z, Liu B, Gao D, Xie C (2007) Adv. Mater. 19:2370

    Article  CAS  Google Scholar 

  25. Chen Y, Qian Z, Zhang Z (2007) Chem. Lett. 36:944

    Article  CAS  Google Scholar 

  26. Jeong U, Im SH, Camargo PHC, Kim JH, Xia Y (2007) Langmuir 23:10968

    Article  CAS  Google Scholar 

  27. Chaiyasat P, Ogino Y, Suzuki T, Okubo M (2008) Colloid Polym. Sci. 286:753

    Article  CAS  Google Scholar 

  28. Okubo M, Minami H (2000) Macromol. Symp. 150:201

    Article  CAS  Google Scholar 

Download references

Acknowledgment

This work was supported by Grant-in-Aid for Scientific Research (Grant No.17201025) from the Japan Society for the Promotion of Science (JSPS).

Author information

Authors and Affiliations

  1. Graduate School of Engineering, Kobe University, Kobe, 657-8501, Japan

    Yuko Hata, Toyoko Suzuki, Hideto Minami & Masayoshi Okubo

Authors
  1. Yuko Hata
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Toyoko Suzuki
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Hideto Minami
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Masayoshi Okubo
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Masayoshi Okubo.

Additional information

Part CCCXV of series “Studies on Suspension and Emulsion”

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hata, Y., Suzuki, T., Minami, H. et al. Preparation of hollow poly(divinyl benzene) particles with multiple holes in the shell by microsuspension polymerization with the SaPSeP method. Colloid Polym Sci 286, 1561–1567 (2008). https://doi.org/10.1007/s00396-008-1917-8

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00396-008-1917-8

Keywords

Search

Navigation