Abstract
Transparent nano-glass-ceramics containing KYF4 nanocrystals were successfully obtained by the sol–gel method, doped with Eu3+ and co-doped with Yb3+ and Tm3+ ions. Precipitation of cubic KYF4 nanocrystals was confirmed by X-ray diffraction and high-resolution transmission electron microscope images. Excitation and emission spectra let us to discern between ions into KYF4 nanocrystals and those remaining in a glassy environment, supplemented with time-resolved photoluminescence decays, that also clearly reveal differences between local environments. Unusual high-energy up-conversion emissions in the UV range were obtained in Yb3+–Tm3+ co-doped samples, and involved mechanisms were discussed. The intensity of these high-energy emissions was analyzed as a function of Yb3+ concentration, heat treatment temperature of precursor sol–gel glasses and pump power, determining the optimum values for potential optical applications as highly efficient UV up-conversion materials in UV solid-state lasers.
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S. Sivakumar, F. Veggel, P. May, J. Am. Chem. Soc. 129, 620 (2007)
Y. Wang, W. Qin, J. Zhang, C. Cao, J. Zhang, S. Lü, Y. Jin, G. Wei, G. Wang, L. Wang, Chem. Lett. 36, 86 (2007)
X. Wang, J. Zhuang, Q. Peng, Y. Li, Inorg. Chem. 45, 6661 (2006)
G. De, W. Qin, J. Zhang, J. Zhang, Y. Wang, C. Cao, Y. Cui, J. Solid State Chem. 179, 955 (2006)
C. Cao, W. Qin, J. Zhang, Y. Wang, P. Zhu, G. Wei, G. Wang, R. Kim, L. Wang, Opt. Lett. 33, 857 (2008)
A. Peng, E. Xie, C. Jia, R. Jiang, H. Lin, Mater. Lett. 59, 3866 (2005)
P.Y. Jia, J. Lin, M. Yu, J. Lumin. 122, 134 (2007)
P. Dorenbos, J. Lumin. 122, 315 (2007)
Q. Chen, X. Wang, F. Chen, Q. Zhang, B. Dong, H. Yang, G. Liu, Y. Zhu, J. Mater. Chem. 21, 7661 (2011)
J.F. Suyver, J. Grimm, M.K. van Veen, D. Biner, K.W. Krämer, H.U. Güdel, J. Lumin. 117, 1 (2006)
N.M. Khaidukov, M. Kirm, S.K. Lam, D. Lo, V.N. Makhov, G. Zimmerer, Opt. Commun. 184, 183 (2000)
L. Bonelli, A. Toncelli, A. Di Lieto, M. Tonelli, J. Phys. Chem. Solids 68, 2381 (2007)
T.R. Park, T.Y. Park, S.H. Youn, N.M. Khaidukov, J. Lumin. 106, 281 (2004)
L. Huang, T. Yamashita, R. Jose, Y. Arai, T. Suzuki, Y. Ohishi, Appl. Phys. Lett. 90, 131116 (2007)
Y. Wang, J. Ohwaki, Appl. Phys. Lett. 63, 3268 (1993)
M.J. Dejneka, J. Non-Cryst. Solids 239, 149 (1998)
X. Qiao, X. Fan, M. Wang, X. Zhang, Opt. Mater. 27, 597 (2004)
C.J. Brinker, G.W. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing (Academic Press, San Diego, 1990)
R. Morimo, K. Matae, Mater. Res. Bull. 24, 175 (1989)
M. Jia, J. Zhang, S. Lu, J. Sun, Y. Luo, X. Ren, H. Song, X. Wang, Chem. Phys. Lett. 384, 193 (2004)
X. Qiao, X. Fan, Z. Xue, X. Xu, J. Non-Cryst. Solids 357, 83 (2011)
G. Wang, W. Qin, L. Wang, G. Wei, P. Zhu, R. Kim, Opt. Express 16, 11907 (2008)
H. Schäfer, P. Ptacek, K. Hickmann, M. Prinz, M. Neumann, M. Haase, Russ. J. Inorg. Chem. 54, 1914 (2009)
Y. Wang, Y. Liu, Q. Xiao, H. Zhu, R. Li, X. Chen, Nanoscale 3, 3164 (2011)
H. Schäfer, P. Ptacek, O. Zerzouf, M. Haase, Adv. Funct. Mater. 18, 2913 (2008)
Y.P. Du, Y.W. Zhang, L.D. Sun, C.H. Yan, Dalton Trans. 8574 (2009)
A.C. Yanes, A. Santana-Alonso, J. Méndez-Ramos, J. del-Castillo, V.D. Rodríguez, Adv. Funct. Mater. 21, 3136 (2011)
A. Santana-Alonso, A.C. Yanes, J. Méndez-Ramos, J. del-Castillo, V.D. Rodríguez, J. Non-Cryst. Solids 356, 933 (2010)
J. Méndez-Ramos, V. Lavín, I.R. Martín, U.R. Rodríguez-Mendoza, V.D. Rodríguez, A.D. Lozano-Gorrín, P. Núñez, J. Appl. Phys. 89, 5307 (2001)
S. Cotton, Lanthanide and Actinide Chemistry, Chapter 2, p. 14, Ed. Wiley, West Sussex, England (2006)
A.C. Yanes, J. del-Castillo, J. Méndez-Ramos, V.D. Rodríguez, M.E. Torres, J. Arbiol, Opt. Mater. 29, 999 (2007)
D. Chen, Y. Wang, K. Zheng, T. Guo, Y. Yu, P. Huang, Appl. Phys. Lett. 91, 251903 (2007)
G. Wang, W. Qin, G. Wei, L. Wang, P. Zhu, R. Kim, D. Zhang, F. Ding, K. Zheng, J. Fluorine Chem. 130, 158 (2009)
G. Qin, W. Qin, C. Wu, S. Huang, D. Zhao, J. Zhang, S. Lu, Opt. Commun. 242, 215 (2004)
C. Cao, W. Qin, J. Zhang, Y. Yang, P. Zhu, G. Wang, G. Wei, L. Wang, L. Jin, J. Fluorine Chem. 129, 204 (2008)
W. Guofeng, Q. Weiping, W. Lili, W. Guodong, Z. Peifen, Z. Daisheng, D. Fuheng, J. Rare Earths 27, 330 (2009)
D. Chen, Y. Wang, F. Bao, Y. Yu, J. Appl. Phys. 101, 113511 (2007)
D. Chen, Y. Wang, Y. Yu, P. Huang, Appl. Phys. Lett. 91, 051920 (2007)
J. Méndez-Ramos, A. Santana-Alonso, A.C. Yanes, J. del-Castillo, V.D. Rodríguez, J. Lumin. 130, 2508 (2010)
X. Chen, Z. Song, J. Opt. Soc. Am. B 24, 965 (2007)
S. Obregón, G. Colón, Chem. Commun. 48, 7865 (2012)
M. Zhang, Y. Lin, T.J. Mullen, W. Lin, L.D. Sun, C.H. Yan, T.E. Pattern, D. Wang, G. Liu, J. Phys. Chem. Lett. 3, 3188 (2012)
Acknowledgments
The authors would like to thank to Agencia Canaria de Investigación, Innovación y Sociedad de la Información y Fondo Europeo de Desarrollo Regional (FEDER) (SolSub200801000286) and Ministerio de Ciencia y Tecnología of Spain Government (MAT2009-12079) for financial support.
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Yanes, A.C., Santana-Alonso, A., Méndez-Ramos, J. et al. Structure and intense UV up-conversion emissions in RE3+-doped sol–gel glass-ceramics containing KYF4 nanocrystals. Appl. Phys. B 113, 589–596 (2013). https://doi.org/10.1007/s00340-013-5514-2
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DOI: https://doi.org/10.1007/s00340-013-5514-2